نتایج جستجو برای: cucurbit vegetables
تعداد نتایج: 21028 فیلتر نتایج به سال:
The current study deals with host-guest complex formation between cucurbit [7] urils as host and lansoprazole as guesti using PM3 (semi empirical molecules orbital calculations) also DFT calculations. In this complex, the formation of hydrogen bonding may be occurred through portal oxygen atoms(O2) of cucurbit [7] urils and amine groups (NH 2 )of the drug. The energies of HOMO and LUMO orbital’...
The supramolecular chemistry of cucurbituril, a synthetic receptor, is fascinating because of the remarkable guest binding behavior of the host. Studies in the field, however, have met with limitations, since the only species known was the hexameric macrocyclic compound, cucurbit[6]uril. Recently we synthesized its homologues, cucurbit[n]uril (n = 5, 7, 8), and derivatives. These new members of...
The macrocyclic host cucurbit[7]uril exhibits highly specific inhibitory effects on the activity of proteases, which can be analyzed by a host-substrate complexation model.
Nitrosamine is derived from nitrate and it seems as one of the factors and causes of gastrointestinal cancer in adults and Methemoglobinemia (blue baby syndrome). Eighty percent of nitrate enters to the body through vegetables and fruits, so in this study nitrate concentration in available vegetables and fruits at Shiraz was determined and compared with standard limit. At first, Shiraz city was...
We report a method for blocking interactions between (129)Xe and cucurbit[6]uril (CB6) until activation by a specific chemical event. We synthesized a CB6-rotaxane that allowed no (129)Xe interaction with the CB6 macrocycle component until a cleavage event released the CB6, which then produced a (129)Xe@CB6 NMR signal. This contrast-upon-activation (129)Xe NMR platform allows for modular synthe...
The first example of paramagnetic rotaxane containing cucurbit[6]urils has been reported and characterized both by ESR and NMR spectroscopy.
FRIENDS WITH BENEFITS; NATURAL ENEMIES AND POLLINATORS IN VIRGINIA CUCURBIT PRODUCTION. James M. Wilson & Thomas P. Kuhar, Department of Entomology, Virginia Tech, Blacksburg, Virginia 24061. Cucurbit production in Virginia provides the commonwealth with melons, pumpkins, summer squashes, and cucumbers, all of which are dependent upon adequate pollination for fruit set and development. Growers ...
Guest induced shape change of the cucurbit[8]uril cavity is likely rate limiting in the supramolecular photocatalytic cycle for CB8 mediated photodimerization of 6-methylcoumarin.
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