We have used dielectric spectroscopy to measure the frequency and temperature dependence of the lowfrequency ~0.5 mHz–100 kHz! complex dielectric function «(v) of thin C60 films. A small charge transfer occurs between the C60 and O2 molecules which occupy interstitial spaces of solid C60 exposed to oxygen ~or ambient air!. Due to the large size of the C60 molecules, this small charge transfer c...

A giant amphiphile, which is constructed with an amorphous nano-pyramid (triphenylamine, TPA) and a crystalline nano-sphere (C60), was synthesized. Structural characterization indicates that this pyramid-sphere-shaped amphiphile (TPA-C60 ) forms a solvent-induced ordered phase, in which the two constituent units self-assemble into alternating stacks of two-dimensional (2D) TPA and C60 nano-shee...

We have investigated the adsorption of some amino acids and an oligopeptide by fullerene (C60) and fullerene nanowhiskers (FNWs). C60 and FNWs hardly adsorbed amino acids. Most of the amino acids used have a hydrophobic side chain. Ala and Val, with an alkyl chain, were not adsorbed by the C60 or FNWs. Trp, Phe and Pro, with a cyclic structure, were not adsorbed by them either. The aromatic gro...

In the supramolecular complex H2@C60, the lightest of molecules, H2, is encapsulated inside the most highly symmetric molecule C60. The elegance and apparent simplicity of H2@C60 conceal highly intricate quantum dynamics of the coupled translational and rotational motions of the guest molecule in a nearly spherical nanoscale cavity, which embodies some of the most fundamental concepts of quantu...

the spectroscopic properties of the 2,2,6,6-tetramethyl-piperidine-1-oxyl (tempo) radicalderivatives of the fullerene (c60) were theoretically investigated. the ground state optimizedstructures of the radical adducts of the fullerene were calculated by using dft (b3lyp) with 6-31g(d) level. it was concluded that a 6-6 ring junction of c60 moiety generally covalently links to thepiperidine ring ...

This paper focuses on portfolio risk forecasting in an asymmetrical framework. Risk is defined by two factors; the dependence structure and the volatility. In order to account for asymmetric dependencies, the return series’ interdependence is estimated via a Copula approach rather than the correlation matrix. This allows to capture tightening dependence during market turmoils and loose dependen...

We consider cooperative games with transferable utility (TU-games), in which we allow for a social structure on any coalition, for instance a network, a hierarchical ordering or a dominance relation. For every coalition the relative strength of a player within that coalition is induced by its social structure and is measured by a power function. We call a payoff vector socially stable if there ...

In this paper, we explore the loss data collection exercise for operational risk in Chinese commercial banks from 1999 to first half of 2006. Firstly, the above data are bootstrapped to analyze the capital allocation for a medium-scaled commercial bank in China. Secondly, for every selected cell, we calibrate two truncated distributions to fit the loss severity, one for ‘normal’ losses and the ...

Lagged Duration Dependence in Mixed Proportional Hazard Models We study the non-parametric identification of a mixed proportional hazard model with lagged duration dependence when data provide multiple outcomes per individual or stratum. We show that the information conveyed by the within strata variation can be exploited to nonparametrically identify lagged duration dependence in more general ...

Fullerenes are sparingly soluble in many solvents. The dependence of fullerene’s solubility on molecular structure of the solvent must be understood in order to manage efficiently this class of compounds. To find such dependency ab initio quantum-chemical calculations in combination with quantitative structure–property relationship (QSPR) tool were used to model the solubility of fullerene C60 ...