Platinum particles were grown directly by an electrodeposition process on electrochemically treated carbon paper (CP) for kinetic study of carbon monoxide (CO) desorption. The treatment on CP was performed by applying −2 V for cathodic oxidation over 5 min. Treated CP was characterized by FTIR to investigate the oxygen groups on its surface. CO surface coverage at each temperature was determine...

adsorption of anilofos was studied in four soils (topsoil from alfisol, inceptisol, oxisol and vertisol). the order of adsorption of anilofos was vertisol > oxisol > alfisol > inceptisol. the soil sorption coefficient k and the soil organic carbon sorption coefficient koc are the basic parameters used for describing the environmental fate of the herbicides. in top soil the calculated k values ...

In order to better discuss the influence of pore structure characteristics primary coal on coalbed methane adsorption, suburban and Zhaozhuang in Henan Province were systematically sampled. The analysis method is divided into shooting research experimental analysis. Scanning electron microscope (SEM) was used analyze formation reason micropores, shape, connectivity, size, filling effect adsorpt...

−Singleand bi-solute sorption and desorption of 2-chlorophenol (2-CP) and 2,4,5-trichlorophenol (2,4,5TCP) in montmorillonite modified with hexadecyltrimethyl-ammonium (HDTMA) were investigated by sequential sorption and desorption. Effect of pH on the sequential sorption and desorption was investigated. As expected by the magnitude of octanol : water partition coefficient (K ow ), both sorptio...

Batch experiments were carried out to investigate the effects of initial atrazine concentrations and consecutive desorption steps on the desorption characteristics of atrazine from a sandy loam soil. As initial atrazine concentration increased, the average percentage of atrazine desorption on the sandy loam soil ranged gradually from 23.1% to 38.5% after five consecutive desorption steps. The v...

OBJECTIVES A new desorption method was investigated, which does not require toxic organic solvents. Efficient desorption of organic solvents from activated carbon was achieved with an ananionic surfactant solution, focusing on its washing and emulsion action. METHODS Isopropyl alcohol (IPA) and methyl ethyl ketone (MEK) were used as test solvents. Lauryl benzene sulfonic acid sodium salt (LAS...

The spatial distribution of desorbing O(2) and CO(2) was examined in 193-nm photoinduced reactions in O(2)+CO adlayers on stepped Pt (112)=[(s)3(111)x(001)]. The O(2) desorption collimated in inclined ways in the plane along the surface trough, confirming the hot-atom collision mechanism. In the presence of CO(a), the product CO(2) desorption also collimated in an inclined way, whereas the incl...

We investigated the reaction mechanism of the desorption of single hydrogen from a titanium dioxide surface excited by the tip of a scanning tunneling microscope (STM). Analysis of the desorption yield, in combination with theoretical calculations, indicates the crucial role played by the applied electric field. Instead of facilitating desorption by reducing the barrier height, the applied elec...

Using model catalysts, we demonstrate that CO desorption from Ru surfaces can be switched from that typical of single crystal surfaces to one more characteristic of supported nanoparticles. First, the CO desorption behaviour from Ru nanoparticles supported on highly oriented pyrolytic graphite was studied. Both mass-selected and thermally evaporated nanoparticles were deposited. TPD spectra fro...