A new device is presented for the combinatorial analysis of complex nano-scale material systems. The parallel nano-differential scanning calorimeter (PnDSC) is a micro-machined array of calorimetric cells. This new approach to combinatorial calorimetry greatly expedites the analysis of nano-scale material thermal properties. A power-compensation differential scanning calorimetry measurement is ...

Poly(ethylene adipte) and poly(ethylene adipate)/silica nanocomposite (PEAd/SiO2) containing 3 wt. % SiO2  were prepared by an in situ method. The examinations on the non-isothermal crystallization kinetic behavior have been conducted by means of differential scanning calorimeter (DSC). The Avrami, Ozawa, and combined Avrami and Ozawa equations were applied to describe the crystallization kinet...

Epoxy – Polysulfide copolymers without or with low amounts of epoxy in their structure have poor mechanical properties in oxidative curing system.To strengthen the mechanical properties of polysulfide elastomer inclusion of epoxy resin (Epon828) as hard segment was studied. FT-IR spectroscopy and rheometry were used to verify the formation of epoxy-polysulfide copolymer.  Results obtained f...

344 Abstract− Silver nanoparticles were synthesized by micro emulsion route in W/S ratio of 5 at room temperature. X-ray diffraction (XRD) pattern reveals FCC structure of Ag nanoparticles. Spherical shape of Ag nanoparticles of average particle size 5.0 to 12.0 nm were observed by transmission electron microscopy. FTIR spectra confirmed the presence of Ag−O bonding. Thermal studies were carrie...

The elemental powder mixtures with a nominal composition of Ti50Cu20Ni24Si4B2 can be amorphized under high-energy ball milling. A well-defined glass transition before crystallization appears in the obtained amorphous phase during heating in a differential scanning calorimeter. Awide supercooled liquid region DTx is available to be about 57 K. Crystallization of the ballmilled amorphous phase wa...

This work aims to study the elastocaloric effect in a Cu-Al-Zn shape memory alloy sample. The elastocaloric effect refers to the reversible thermal response (isothermal entropy change, or adiabatic temperature change) of a body when subjected to a uniaxial stress. To measure the entropy change of the martensitic transformation, differential scanning calorimetry technique has been used. The calo...

In this work, we have studied the influence of dc joule-heating thermal processing on the structure, magnetoimpedance (MI) and thermal properties of Co64Fe4Ni2B19-xSi8Cr3Alx (x = 0, 1, and 2) rapidly solidified melt-spun ribbons. The nanocrystallization process was carried out by the current annealing of as-spun samples at various current densities. As-spun and joule-heated samples were studied...

The main objective of the present work was to synthesis polyamide 6 through anionic polymerization of ε-caprolactam in an internal mixer. The reaction time and the rheological properties of samples during the polymerization were studied. The samples were characterized by Thermo Gravimetry Analysis (TGA), Differential Scanning Calorimeter (DSC) and FT-IR spectrometer. The melt flow behavior and ...

We investigated the transport, thermal and magnetic properties of antiferromagnetic (TN = 45 K) Gd2InGe2. Magnetization measurements under applied magnetic field, oriented along different crystallographic directions, were used to extract the anisotropic magnetocaloric effect. We also measured magnetization under pulsed field up to 45 T. From the analysis of the electrical transport and magnetiz...

In this research, hybrid materials based on poly(methyl methacrylate) and silica were synthesized via sol±gel process. Their glass transition behavior was investigated by differential scanning calorimeter. In DSC measurement, 1808C heat-treated hybrid materials exhibited higher miscibility as compared to untreated materials. Relationship between miscibility variation of hybrid materials and hea...