A detailed model is presented for the analysis of temperature, species concentration, and current density profiles as well as the efficiency and power density of a planar solid oxide fuel cell at direct internal reforming condition. The model describes the interactions of mass transport, heat transport, heterogeneous chemistry, and electrochemistry. The heterogeneous chemistry model for the cat...

Heme/porphyrin-based electrocatalysts (both synthetic and natural) have been known to catalyze electrochemical O2, H(+), and CO2 reduction for more than five decades. So far, no direct spectroscopic investigations of intermediates formed on the electrodes during these processes have been reported; and this has limited detailed understanding of the mechanism of these catalysts, which is key to t...

■ CONTENTS Nanoelectrodes 473 Extraordinary Properties of Nanoelectrodes 474 Nanoelectrode Fabrication 474 Nanoskiving 475 Lithographically Patterned Nanowire Electrodeposition 475 SWNT-Templated Nanowires and MCEM 476 Voltammetry and Double Layer Effects on Nanoelectrodes 476 Effect of Electrical Double Layer 476 Nanoparticle Electrochemistry 477 Monolayer Protected Clusters 477 Stochastic Nan...

In this study, we investigated redox thermodynamics of myoglobin as well as the ionic (phosphate ions) and ligation (imidazole) effects via a dynamic electrochemical approach. We employed a previously established system that features nonmediated, direct electrochemistry of myoglobin and myoglobin in an immobilized state (i.e., diffusionless electrochemistry). Thermodynamics parameters were obta...

Electrochemistry provides an array of methods to investigate protein aggregation and determine biomarkers neurodenenerative diseases. Biosensors detecting monomeric or oligomeric Alzheimer's disease Parkinson's evolved toward femtomolar, multiplexed detection in blood biological fluids for less invasive diagnosis. The biosensors also serve as complementary tools studies investigating putative t...

The direct electrochemistry of hemoglobin (Hb) immobilized on a hexagonal mesoporous silica (HMS)-modified glassy carbon electrode was described. The interaction between Hb and the HMS was investigated using UV-Vis spectroscopy, FT-IR, and electrochemical methods. The direct electron transfer of the immobilized Hb exhibited two couples of redox peaks with the formal potentials of -0.037 and -0....

Interactive multimedia module with pedagogical agent (IMMPA) named EC Lab was developed in order to assist students in the learning of Electrochemistry topic. A non-equivalent pre-test post-test control group design investigation was carried out in order to gauge the effect of EC Lab on students’ understanding in the learning of Electrochemistry. Some 127 Form Four students from two secondary s...

The effect of adsorption on molecular properties and reactivity is a central topic in interfacial physical chemistry. At electrochemical interfaces, adsorbed molecules may lose their electrochemical activity. The absence of in situ probes has hindered our understanding of this phenomenon and electrode reactions in general. In this work, classical electrochemistry and electrochemical scanning tu...

Real-time electron microscopy observations of processes in wet environments, i.e., solutions, liquids, etc. have become possible only very recently with the development of electron beam transparent cells, in which a liquid layer is trapped between two ultrathin, electron-transparent membranes. Liquid-cell transmission electron microscopy (TEM) and scanning TEM (STEM) have attracted a lot of int...

Cyclic voltammetry is a fundamental experimental method for characterizing electrochemical surfaces. Despite its wide use, a way to quantitatively and directly relate cyclic voltammetry to ab initio calculations has been lacking. We derive the cyclic voltammogram for H on Pt(111) and Pt(100), based solely on density functional theory calculations and standard molecular tables. By relating the g...