An array of analytical methods including surface area determination by gas adsorption using the Brunauer, Emmett, Teller (BET) method, combustion analysis, XRD, ToF-SIMS, TEM and impedance spectroscopy has been used to investigate the interaction of gadolinia doped ceria (GDC) with hydrogen sulphide containing reducing atmospheres. It is shown that sulphur is incorporated into the GDC bulk and ...

We show the design and synthesis of new perfluorinated nitrosopyrazolone-based ligands and the original method employed for their complexation of erbium ions in the presence of the co-ligand perfluorotriphenylphosphine oxide; the resulting chelate is non-hygroscopic, solution processable and possesses a NIR emission with lifetimes as long as 16 micros.

INTRODUCTION The aim of this study was to evaluate the effect of dental surface treatment with Erbium-Doped Yttrium Aluminum Garnet(Er: YAG), Neodymium-Doped Yttrium Aluminium Garnet(Nd: YAG) and Carbon Dioxide Laser (CO2) lasers and sodium ascorbate to recently home bleached enamel by scanning electron microscope (SEM). METHODS Thirty extracted human third molars were selected for this in vi...

A new laser heating system has been set up to minimize the sample temperature gradients both radially and axially in a diamond anvil cell. A multimode Nd:YAG laser with a relatively flat top of intensity profile allows us to reduce the radial temperature gradient; the axial temperature gradient is minimized by heating samples at both sides. Three dimensional uniform temperatures of 1200 4000 K ...

Conventional PET methods to estimate [(11)C]raclopride binding potential (BP ND) assume that endogenous dopamine concentration does not change during the scan time. However, this assumption is purposely violated in studies using pharmacological or behavioral stimuli to invoke acute dopamine release. When the assumption of steady-state dopamine is violated, conventional analysis methods may prod...

Prediction of the extent and time course of drug-drug interactions (DDIs) between the mechanism-based inhibitor diltiazem (DTZ) and the CYP3A4 substrate midazolam (MDZ) is confounded by time- and concentration-dependent clearance of the inhibitor. Semiphysiologically based pharmacokinetic (PBPK) models were developed for DTZ and MDZ with the major metabolite of DTZ, N-desmethyldiltiazem (nd-DTZ...

Er3+-doped fluorozirconate (ZrF4-BaF2-YF3-AlF3) and oxyfluoroaluminate glasses are successfully prepared here. These glasses exhibit significant superiority compared with traditional fluorozirconate glass (ZrF4-BaF2-LaF3-AlF3-NaF) because of their higher temperature of glass transition and better resistance to water corrosion. Judd-Ofelt (J-O) intensity parameters are evaluated and used to comp...

Mixtures of yttrium acetate hydrate (Y(O2CCH3)3?4H2O) and aluminum formate hydrate (Al(O2CH)3?3H2O in H2O) or yttrium isobutyrate (Y[O2CCH(CH3)2]3) and aluminum isobutyrate (Al[O2CCH(CH3)2]3) in tetrahydrofuran were used as precursors to process yttrium aluminum garnet (YAG, Al5Y3O12) fibers. The pyrolytic decomposition patterns of Al(O2CH)3?3H2O, Y(O2CCH3)3?4H2O, and a [3Y(O2CCH3)3?4H2O/5Al(O2...

Melasma is an acquired disorder of pigmentation that commonly affects women with phototypes III-V, and it has a negative impact on the quality of life in affected individuals. It presents clinically as symmetric tan or brown patches on the face, most often involving the forehead, cheeks, perioral region, and periorbital region. On histologic examination, there is increased melanin in the epider...

Scars following trauma [1] is a cause of concern for many a patient. Various modalities have been used for the treatment of scars over the years. Corticosteroids, dermabrasion, surgical revision, chemical peeling, silicone gel application, pressure therapy, and radiation have been used with varying results [2]. Ablative lasers such as the carbon dioxide (CO2), erbium: yttrium-aluminum-garnet (E...