sulfonic acid functionalized sba-15 (sba-pr-so3h) as a new nanoporous acid catalyst was used in the one-pot synthesis of polyhydroquinolines derivatives via the hantzsch four component condensation reaction of aldehydes, b-ketoesters, dimedone and ammonium acetate under solvent free conditions with short reaction time in excellent yields. sba-pr-so3h was proved to be an efficient heterogeneous ...

Flavanone was synthesized through the Claisen–Schmidt condensation between benzaldehyde and acetophenone and subsequent intramolecular Michael addition over aminopropyl-functionalized SBA-15 materials. The catalysts with well-ordered hexagonally arranged mesopores were synthesized by one-pot co-condensation of tetraethoxysilane and aminopropyltriethoxysilane using amphiphilic block copolymer as...

A novel SBA-15-functionalized TEMPO confined ionic liquid [BMIm]Br was found to be a highly efficient and recyclable catalyst system for the transition-metal-free aerobic oxidation of a wide range of structurally diverse alcohols. Thanks to the strong physical confinement of the ionic liquid inside the mesochannels of SBA-15-supported TEMPO, the resulting solid catalyst showed improved selectiv...

Acid-Functionalized SBA-15-Type Silica Catalysts for Carbohydrate Dehydration Anthony J. Crisci, Mark H. Tucker, Ming-Yung Lee, Se Gyu Jang, James A. Dumesic,* and Susannah L. Scott* Department of Chemistry & Biochemistry, Department of Chemical Engineering, and Materials Research Laboratory, University of California, Santa Barbara, California 93106, United States Department of Chemical Enginee...

the surface of sba-15 was modified by diphenylphosphine; then, it was treated with butane sultone and sulfuric acid to obtain brønsted acid ho3s-phosphonium based ionic liquid functionalized sba-15 with hso4- as a counteranion. it efficiently catalyzed synthesis of pyrano[3,2-c]chromenone derivatives through the reaction of 4-hydroxycoumarin and chalcones at 60 °c in water/ethanol. good yields,...

Sulfonic acid functionalized SBA-15 (SBA-Pr-SO3H) as a new nanoporous acid catalyst was used in the one-pot synthesis of polyhydroquinolines derivatives via the Hantzsch four component condensation reaction of aldehydes, b-ketoesters, dimedone and ammonium acetate under solvent free conditions with short reaction time in excellent yields. SBA-P...

A new method for the preparation of well-defined functionalized mesoporous SBA-15 has been developed by a one-step co-condensation method using trimethallylsilanes as organosilane sources. This new method enables the incorporation of various bulky organic functional groups with long alkyl chain tethers into the mesoporous silica network.