A new family of Y(4)/M(2) and Y(5)/M heterobimetallic rare-earth-metal/d-block-transition-metal-polyhydride complexes has been synthesized. The reactions of the tetranuclear yttrium-octahydride complex [{Cp''Y(μ-H)(2)}(4)(thf)(4)] (Cp'' = C(5)Me(4)H, 1-C(5)Me(4)H) with one equivalent of Group-6-metal-pentahydride complexes [Cp*M(PMe(3))H(5)] (M = Mo, W; Cp* = C(5)Me(5)) afforded pentanuclear he...

Reactions of scandium terminal imido complexes with CuI and [M(COD)Cl](2) (M = Rh, Ir) show two interesting reaction patterns, and the formed heterobimetallic complexes have intriguing structural features and show promising catalytic properties.

We herein discuss the use of 1,1-diphosphineamide ligands for synthesis mono- and heterobimetallic complexes Rh(I) Ti(IV) metal centers. A small library monometallic species was sy...

A chiral-at-metal Ir(III) organometallic metallatecton was synthesised as a racemic mixture and as enantiopure complexes and combined with Cu(II) to afford a heterobimetallic (Ir,Cu) grid-type 2D coordination network.

A mesoionic carbene with a ferrocene backbone is used as a metalloligand to generate the first example of their Fe-Au heterobimetallic complexes. The details of geometric and electronic structures in different redox states and preliminary catalytic results are presented.

SYNLETT 2005, No. 4, pp 0545–055904.03.2005 Advanced online publication: 22.02.2005 DOI: 10.1055/s-2005-862380; Art ID: A36604ST © Georg Thieme Verlag Stuttgart · New York Abstract: In this account, we survey our work on the use of transition metal nanoparticles as catalysts in Pauson–Khand-type reactions. Cobalt nanoparticles and Co/Ru, Co/Rh, and Co/Pd heterobimetallic nanoparticles have been...

The bismuth-catalyzed urethane reaction is significantly accelerated by generating heterobimetallic mixtures of bismuth and lithium carboxylates.