The dynamics of an electron's wave packet on hydrogenated graphene at low hydrogen coverages has been simulated using the tight-binding model. It is found that the bonding between the hydrogen and carbon atoms induces an impurity electron state at an energy of ≈ 0.14 eV above the Dirac crossing energy ED, at which the impurity's scattering of electrons is resonantly enhanced. The asymmetry foun...

The so-called graphane is a fully hydrogenated form of graphene. Because it is fully hydrogenated, graphane is expected to have a wide bandgap and is theoretically an electrical insulator. The transition from graphene to graphane is that of an electrical conductor, to a semiconductor, and ultimately to an electrical insulator. This unique characteristic of graphane has recently gained both acad...

A porous graphene paper was prepared by pressing a graphene cryogel, followed by thermal reduction at 220 °C. The cryogel was formed by freeze-drying a solution containing chemically reduced graphene and graphene oxide (CRG/GO). The formed graphene cryogel papers deliver a much higher discharge capacity and rate capability than that from conventional graphene papers fabricated by filtration. Th...

We report on the magnetic properties of single Co atoms on graphene on Pt(111). By means of scanning tunneling microscopy spin-excitation spectroscopy, we infer a magnetic anisotropy of K=-8.1  meV with out-of-plane hard axis and a magnetic moment of 2.2μ(B). Co adsorbs on the sixfold graphene hollow site. Upon hydrogen adsorption, three differently hydrogenated species are identified. Their ma...

We study molecular mobility on a graphene nanoroad (GNRD), a pristine graphene strip embedded in between two hydrogenated graphene domains serving as a nanoscale pathway for transporting admolecules. Our molecular dynamics simulations using a prototype physisorbed C60 admolecule demonstrate that the proposed GNRD is able to confine the diffusive motion of the admolecule within the nanoroad up t...

We perform a comparative study of the spin relaxation by spin-orbit coupling induced from adatoms (hydrogen and fluorine) in graphene. Two methods are applied, giving consistent results: a full quantum transport simulation of a graphene nanoribbon, and a T-matrix calculation using Green’s functions for a single adatom in graphene. For hydrogenated graphene the dominant spinorbit term for spin r...

Supercapacitors with porous electrodes of graphene macroscopic assembly are supposed to have high energy storage capacity. However, a great number of "close pores" in porous graphene electrodes are invalid because electrolyte ions cannot infiltrate. A quick method to prepare porous graphene electrodes with reduced "close pores" is essential for higher energy storage. Here we propose a wet-spinn...

Porous materials have historically been of interest for a wide range of applications in thermal management, for example, in heat exchangers and thermal barriers. Rapid progress in electronic and optoelectronic technology necessitates more efficient spreading and dissipation of the heat generated in these devices, calling for the development of new thermal management materials. Here, we report a...

Hybridized two-dimensional materials incorporating domains from the hexagonal boron nitride (h-BN) and graphene is an interesting branch of materials science due to their highly tunable electronic properties. In the present study, we investigate the hydrogenated two-dimensional (2D) h-BN/C superlattices (SLs) with zigzag edges using first-principles calculations. We found that the domain width,...