The objective of this study was to examine the pore-scale distribution and morphology of organic immiscible liquid in natural porous media containing three immiscible fluids. High-resolution, threedimensional images of an organic liquid (tetrachloroethene) in both three-phase (water–air–organic liquid) and two-phase (water–organic liquid) systems were obtained using synchrotron X-ray microtomog...

The flow of two immiscible fluids in porous media is ubiquitous particularly in petroleum exploration and extraction. The displacement of one fluid by another immiscible with it represents a very important aspect in what is called enhanced oil recovery. Another example is related to the long-term sequestration of carbon dioxide, CO2, in deep geologic formations. In this technique, supercritical...

A lattice Boltzmann high-density-ratio model, which uses diffuse interface theory to describe the interfacial dynamics and was proposed originally by Lee and Liu [T. Lee, L. Liu, Lattice Boltzmann simulations of micron-scale drop impact on dry surfaces, J. Comput. Phys. 229(2010) 8045-8063], is extended to simulate multiphase flows in porous media. A wetting boundary treatment is proposed for t...

In 1971, Starks introduced the term “phase-transfer catalysis” to explain the critical role of tetraalkylammonium or phosphonium salts (QþX ) in the reactions between two substances located in different immiscible phases [1]. For instance, the displacement reaction of 1-chlorooctane with aqueous sodium cyanide is accelerated many thousand-fold by the addition of hexadecyltributylphosphonium bro...

In this article, we study the existence of solutions to a nonlinear degenerate system modelling the displacement of two-phase compressible immiscible flow in a three dimensional porous media. The aim of this work is to treat the model with its general form with the whole nonlinear terms. Especially, we consider the case where the density of each phase depends on its corresponding pressure. We d...

We investigate pattern formation in the immiscible displacement of foam from a confining geometry. The dominant length scales with the driving pressure gradient as for a Newtonian fluid, but depends surprisingly on the ratio of plate separation to bubble diameter. The pattern morphology exhibits a transition from a jagged, presumably elastic, character to a smooth, viscous character as the shea...

We present a three-dimensional network model to simulate two- and three-phase capillary dominated processes at the pore level. The displacement mechanisms incorporated in the model are based on the physics of multiphase flow observed in micromodel experiments. All the important features of immiscible fluid flow at the pore scale, such as wetting layers, spreading layers of the intermediate-wet ...

The concept of immiscible displacement as an invasion percolation (IP) process driven by heat and mass transfer is used in a pore network model for convective drying of capillary porous media. The coupling between heat and mass transfer occurs at the liquid-gas interface through temperature dependent equilibrium vapour pressure, surface tension and phase change enthalpy (in evaporation and cond...

Wettability alteration that occurs as a result of changing the brine composition or using chemicals lower interfacial tension can significantly alter mobility nonaqueous liquid (NAPL)/water phases. Here, we show including dynamic wettability alternation (moving from non-water-wet to water-wet) interpolating between two sets relative permeability curves may create an unstable displacement reside...