One of the most promising anode materials for solid oxide electrolysis cell (SOEC) application is the Sr-doped LaMnO3 (LSM) which is known to have a high electronic conductivity but low ionic conductivity. To increase the ionic conductivity or diffusion of ions through the anode, Yttria-stabilized Zirconia (YSZ), which has good ionic conductivity, is proposed to be combined with LSM to create a...

Ionic liquid crystals (ILCs) allow the combination of the high ionic conductivity of ionic liquids (ILs) with the supramolecular organization of liquid crystals (LCs). ILCs salts were obtained by the assembly of long-chained diketonylpyridinium cations of the type [HOOR(n)pyH]⁺ and BF₄-, ReO₄-, NO₃-, CF₃SO₃-, CuCl₄2- counter-ions. We have studied the thermal behavior of five series of compounds...

Ammonium-based benzyl-NX3 (X = methyl, ethyl) trifluoromethanesulfonate (TFA) ionic liquids (ILs) are low cost, nontoxic, thermally stable ion-conducting electrolytes in fuel cells and batteries. In the present study, we have characterized the structure and dynamics of these ILs using molecular dynamics (MD) simulations and ionic conductivity using electro-chemical impedance spectroscopy (EIS) ...

We describe a two-dimensional (2D) and a three-dimensional (3D) percolation model for ionic conductor-insulator composites such as copper(I) bromide-titanium dioxide (CuBr-TiO2) or lithium iodidealumina (LiI-Al2O3). These composites present an enhanced conductivity closely related to the insulator concentration. This effect is explained by the formation of highly conducting space charge regions...

High ionic conductivity solid polymer electrolyte (SPE) has long been desired for the next generation high energy and safe rechargeable lithium batteries. Among all of the SPEs, composite polymer electrolyte (CPE) with ceramic fillers has garnered great interest due to the enhancement of ionic conductivity. However, the high degree of polymer crystallinity, agglomeration of ceramic fillers, and...

Polymer-supported ionic liquids (ionogels) are emergent, nonvolatile electrolytes for electrochemical energy storage applications. Here, chemical and physical interactions between the ionic liquid 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (EMI TFSI) and three different cross-linked polymer scaffolds with varying chemical functional groups have been investigated in ionogels f...

An yttria stabilised zirconia which exhibits a coreshell microstructure was investigated as a method to produce a zirconia with high ionic conductivity and improved thermal shock resistance. Zirconia grains consist of an outer shell of tetragonal zirconia with an inner core of monoclinic phase zirconia. Impedance spectroscopy was used to identify the e€ect of processing conditions on the grain ...

Common analysis (level 1) characterizes the degree of ion association in polymer electrolytes by the Nernst-Einstein deviation parameter ∆ which quantifies the relative difference between the true ionic conductivity directly measured by electrical methods and the hypothetical maximum conductivity calculated from the individual ionic self-diffusion coefficients. Alternatively, the Haven ratio HR...

A large number of AgI-based fast-ion-conducting glasses have been investigated by K-iodine extended x-ray absorption fine structure spectroscopy (EXAFS) measurements at liquid nitrogen temperature. A general correlation between the I-Ag distance measured by EXAFS and the glass activation energy for dc ionic conductivity has been found out: glasses with longer I-Ag distances display higher ionic...

The Li+ ion diffusion coefficient of lithium iron phosphate LiFePO4 cathode materials should not be measured by the standard method because there is no composition variation but the movement of the LiFePO4/FePO4 interface during Li insertion/ extraction. A method to measure the intrinsic electronic and ionic conductivity of mixed conductive LiFePO4 was reported, for the first time, based on the...