نتایج جستجو برای: langmuir hinshelwood model
تعداد نتایج: 2108823 فیلتر نتایج به سال:
the photocatalytic degradation of betamethasone sodium phosphate was investigated in aqueoussuspensions of zinc oxide nanoparticular with diameter size 20 nm under a variety of conditions.different parameters such as irradiation time, the amount catalyst (0.12-0.8 g lh), initialconcentration of drug (10-50 mgljand initial ph values (ranging from 3 to ii) were investigatedin the presence of vari...
The degradation of pyridine, widely used in the synthesis of vitamins, drugs, rubber chemicals, herbicides and pesticides, can be photocatalyzed by semiconductor catalysts. Since zinc oxide promotes faster pyridine photocatalytic oxidation reactions than TiO2, the former appears to be a suitable alternative to TiO2 for water treatment contaminated with pyridine. The photodegradation efficiency ...
The photocatalytic degradation of phenol in a static-batch photoreactor, using a UV lamp as a light source and TiO 2 as a photocatalyst, was investigated. The effects of various parameters, such as photocatalyst dosage, initial substrate concentration, reaction pH and addition of oxidants, on the phenol degradation rate of TiO 2 photocatalysis were examined. The degradation rates proved to be s...
The objective of this study was to examine the effects of adsorbability and number of sulfonate group on solar photocatalytic degradation of mono azo methyl orange (MO) and diazo Reactive Green 19 (RG19) in single and binary dye solutions. The adsorption capacity of MO and RG19 onto the TiO₂ was 16.9 and 26.8 mg/g, respectively, in single dye solution, and reduced to 5.0 and 23.1 mg/g, respecti...
MXenes have attracted considerable attention owing to their versatile and excellent physicochemical properties. Especially, they potential applications as robust support for single atom catalysts. Here, quantum chemical studies with density functional theory are carried out systematically investigate the geometries, stability, electronic properties of oxygen functionalized Ti2C (Ti2CO2) support...
In this paper, the photocatalytic decoloration of Acid Red 27 (AR27) has been investigated using ultraviolet (UV) irradiation in presence of SnO2 nanoparticles. SnO2 nanoparticles were synthesized via hydrothermal process. The SnO2 nanoparticles' average crystallite sizes derived from X-ray analyses which were synthesized for 2, 12 and 24 hrs were about 3.73, 5.31 and 7.6 nm, respectively. Brun...
In this study, photocatalytic degradation of phenol by titanium dioxide (TiO2) in aqueous solution was evaluated. The UV energy of solar light was utilized by compound parabolic collectors (CPCs) technology. The effect of irradiation time, initial pH, and dosage of TiO2 were investigated. Aromatic intermediates (catechol, benzoquinone, and hydroquinone) were quantified during the reaction to st...
Kinetic study for different start up conditions of the anaerobic digestion of wastewater derived from the sago processing from tubers of tapioca (Mannihot utillisema) is discussed. The experiment is carried out with synthetic waste water using a tapered fluidized bed reactor. Mesoporous granulated activated carbon is used as a bacterial support. The kinetic model follows half order kinetics for...
This study aimed at improving the photocatalytic (PC) oxidation of humic acids (HA) in TiO2 suspensions by adding cationic ion such as calcium or magnesium. A set of tests was first conducted in the dark to study the adsorption of HA onto TiO2 in suspensions at different pH and calcium concentrations. The experiment demonstrated that the adsorption of HA onto the TiO2 particles was either pH-de...
This study developed an upgrading process focusing on acid transformations of water phase pyrolysis bio-oils to esters of oxygen-containing fuels via ZSM−5 catalyst. Temperature was set as a factor with five levels ranging from 60 to 135 °C with reaction time from 1 to 8 h. The results showed that 89% of high acid conversion and over 90% of ester selectivity was obtained from the feedstock via ...
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