Electrolytes confined in nanochannels with characteristic dimensions comparable to the Debye length show transport behaviors deviating from their bulk counterparts. Fabrication of nanofluidic devices typically relies on expensive lithography techniques or the use of sacrificial templates with sophisticated growth and processing steps. Here we demonstrate an alternative approach where unpreceden...

As the cylindrical sp(2)-bonded carbon allotrope, carbon nanotubes (CNTs) have been widely used to reinforce bulk materials such as polymers, ceramics, and metals. However, both the concept demonstration and the fundamental understanding on how 1D CNTs reinforce atomically thin 2D layered materials, such as graphene, are still absent. Here, we demonstrate the successful synthesis of CNT-toughen...

a modified electrode was prepared by modification of the carbon paste electrode (cpe) with graphene nano-sheets. the fabricated modified electrode exhibited an electrocatalytic activity toward gallic acid (ga) oxidation because of good conductivity, low electron transfer resistance and catalytic effect. the graphene modified cpe had a lower overvoltage and enhanced electrical current respect to...

We present a general study on a high performance supercapacitor based on intercalated reduced graphene oxide with carbon black nanoparticles. Graphene oxide sheets were synthesized by oxidation and exfoliation of natural graphite and were reduced using hydroiodic acid in the presence of carbon black nanoparticles. Graphene paper was fabricated by one-step procedure via simultaneous reducing and...

The toughness and coefficient of thermal expansion of a series of functionalized graphene sheet epoxy nanocomposites are investigated. Functionalized graphene sheets are produced by splitting graphite oxide into single graphene sheets through a rapid thermal expansion process. These graphene sheets contain ~ 10% oxygen due to the presence of hydroxide, epoxide, and carboxyl functional groups wh...

bending analysis of multilayer graphene sheets (mlgss) subjected to non-uniform shear and normal tractions is presented. the constitutive relations are considered to be non-classical based on nonlocal theory of elasticity. based on the differential transformation method, numerical illustrations are carried out for circular and annular geometries. the effects of nano scale parameter, radius of c...

This paper addresses the influence of boundary conditions and small-scale effect on the free vibration of nano-plates using molecular dynamics (MD) and nonlocal elasticity theory. Based on the MD simulations, Large-scale Atomic/Molecular Massively Parallel Simulator (LAMMPS) is used to obtain fundamental frequencies of single layered graphene sheets (SLGSs) which modeled in this paper as the mo...

In the present study, potential of finite element based molecular structural mechanics (MSM) for evaluating stress concentration factor of single-layered graphene sheets (SLGSs) with elliptical vacancies is successfully addressed. The MSM approach mimics the interatomic forces of the nanostructure by defining an equivalent frame structure containing beam elements. To obtain the mechanical and c...

Graphene-based membranes demonstrating ultrafast water transport, precise molecular sieving of gas and solvated molecules shows great promise as novel separation platforms; however, scale-up of these membranes to large-areas remains an unresolved problem. Here we demonstrate that the discotic nematic phase of graphene oxide (GO) can be shear aligned to form highly ordered, continuous, thin film...

Hexagonal boron nitride (h-BN) is an insulating compound that is structurally similar to graphite. Like graphene, single sheets of BN are atomically flat, and they are of current interest in few-layer hybrid devices, such as transistors and capacitors, that contain insulating components. While graphite and other layered compounds can be intercalated by redox reactions and then converted chemica...