The reduction mechanism of molybdenum-methyl thymol blue (MTB)-chlorate system has been investigated in water on a mercury electrode. As this system is very sensitive for ultratrace determination of molybdenum, the actual mechanism involved was studied. Electrochemical techniques, including dc tast polarography and cyclic voltammetry were employed. It is shown that, the cathodic wave of mol...

The crystal structures of three complexes [HgCl2 L] were determined, namely, (S)-(+)-di-chlorido-[1-phenyl-N-(pyridin-2-yl-methyl-idene)ethyl-amine-κ(2) N,N']mercury(II), [HgCl2(C14H14N2)], (S)-(+)-di-chlorido-[1-(4-methyl-phen-yl)-N-(pyridin-2-yl-methyl-idene)ethyl-amine-κ(2) N,N']mercury(II), [HgCl2(C15H16N2)], and (1S,2S,3S,5R)-(+)-di-chlorido-[N-(pyridin-2-yl-methyl-idene)isopino-camph-eyl-...

Mercury (Hg) is a naturally occurring element that has metallic, inorganic and organic forms, each with their own implications for human health. Exposure to mercury primarily occurs by inhalation of metallic mercury vapors and by dietary intake of organic mercury. Early health effects are often not well detected. Therefore, determination of the internal dose is a valuable approach in primary pr...

The three modern "faces" of mercury are our perceptions of risk from the exposure of billions of people to methyl mercury in fish, mercury vapor from amalgam tooth fillings, and ethyl mercury in the form of thimerosal added as an antiseptic to widely used vaccines. In this article I review human exposure to and the toxicology of each of these three species of mercury. Mechanisms of action are d...

Water quality impairment due to high mercury fish tissue concentrations and high mercury aqueous concentrations is a widespread problem in several sub-watersheds that are major sources of mercury to the San Francisco Bay. Several mercury Total Maximum Daily Load regulations are currently being developed to address this problem. Decisions about control strategies are being made despite very larg...

It has been reported that mercury was contained in the tissue of, and eggs laid by hens fed experimentaly seed grains treated with methyl mercury dicyandiamide (1, 2). In the field, it has also been pointed out the remarkably high mercury contents in seed-eating birds, such as pheasants, and predatory animals living on such birds, suggesting that it may be explained by the existence of alkyl me...

Glabrin (2-Piperidine, carboxylic acid, 4, 5, dihydroxy, -1-methyl) was isolated from Pongamia glabra seeds and metal complexes were prepared by refluxing with acetates of cupper, zinc and mercury, estimation was carried out by simple idometric method for copper complex and E.D.T.A. method for zinc and mercury complexes of glabrin. Results of present study reveal that the metal complexes show c...