We propose a new theoretical scheme for the binary phase diagrams of crystal-liquid crystal mixtures by a combination of a phase field model of solidification, the Flory-Huggins theory for liquid-liquid mixing and Maier-Saupe-McMillan (FH-MSM) model for nematic and smectic liquid crystal orderings. The phase field theory describes the crystal phase transition of anisotropic organic crystal and/...

We show that a spontaneous bending of single-layer bolaamphiphiles results from the frustration due to the competition between core-core and tail-solvent interactions. We find that spherical vesicles are stable under rather general assumptions on these interactions described within the Flory-Huggins theory. We consider also the deformation of the vesicles in an external magnetic field that has ...

2014 The phase equilibrium in polymer-solvent systems has been described in terms of the Landau-Ginzburg-Wilson model. The scaling law for the coexistence curve which has been derived in the present article is in good agreement with the experimental data. The prediction of the present theory that the scaling region narrows with increasing degree of polymerization, is consistent with the experim...

The Flory-Huggins interaction is measured for a model rod-coil block copolymer system, poly(alkoxyphenylenevinylene-b-isoprene), by fitting the interfacial segregation of block copolymer to a homopolymer interface and by using the random phase approximation (RPA) for block copolymers. The measured interfacial segregation of a block copolymer to the interface between homopolymers, fit with a sel...

In this study, the drying kinetics of granular nylon-6 has been investigated. Single particle drying experiments were carried out in a magnetic suspension balance (MSB) using dry air as drying agent. The comparison of measured and simulated data using Vrentas-Duda diffusion model shows a satisfactory prediction of mean particle moisture content and drying rates. The Flory-Huggins model predicts...

We present an analysis of the equilibrium diiusive interfaces in a model for the interaction of layers of pure polymers. The discussion focuses on the important qualitative features of the solutions of the nonlinear singular Cahn-Hilliard equation with degenerate mobility for the Flory-Huggins-de Gennes free energy model. The spatial structure of possible equilibrium phase separated solutions a...

Evaluation of a surface equation of state generally involves an evaluation of its ability to represent raw experimental data, or information derived from such data, after the parameters of the equation have been adjusted to optimize this representation, followed by an evaluation of the physical reasonableness of the optimizing parameters in terms of the physical model on which the equation of s...

The sorption of carbon dioxide in poly(lactic acid) (PLA) was studied by quartz crystal microbalance at high pressures. To address the effect of the D isomer present in the polymer on the gas sorption, measurements were performed in PLA with two different L:D contents, 80:20 and 98:2. New data for the solubility of carbon dioxide in PLA 80:20 and PLA 98:2 over a temperature range from 303.2 to ...