The structure of molten LaBr3 was investigated by X-ray diffraction and molecular dynamics simulations. It was found that the short range structure of molten LaBr3 is very similar to that of molten LaCl3, except for some structural features such as interionic distances based on the difference of anion sizes. In the MD simulation, the shear viscosity of molten LaBr3 was estimated from the struct...

In general, when a crystal is molten, all molecules forget about their mutual correlations and long-range order is lost. Thus, a regrown crystal does not inherit any features from an initially present crystal. Such is true for materials exhibiting a well-defined melting point. However, polymer crystallites have a wide range of melting temperatures, enabling paradoxical phenomena such as the coe...

The use of biodegradable polymers in tissue engineering has been widely researched due to their ability degrade and release components a controlled manner, allowing for the potential regeneration tissues. Melt blending is common method controlling degradation rate these polymers, which involves combining materials molten state create homogenous mixture with tailored properties. In this study, p...

In the thermal spraying process, the process for the molten metal particles to hit against matrix to form coating experiences great change temperature. Since the coating materials has different thermal physical properties with the matrix materials, the residual stress is surely left in the coating. Much bigger residual stress not only restricts coating thickness but also primarily affects coati...

Nuclear magnetic resonance (NMR) spectroscopy is a powerful technique for the study of the structure, dynamics, and folding of proteins in solution. It is particularly powerful when applied to dynamic or flexible systems, such as partially folded molten globule states of proteins, which are not usually amenable to X-ray crystallography. In this article, NMR methods suitable for the detailed cha...

cazro3 nanoceramics were successfully synthesized at 700 c using the molten salt method, and the effects of processing parameters, such as temperature, holding time, and amount of salt on the crystallization of cazro3 were investigated. cacl2, na2co3, and nano-zro2 were used as starting materials. on heating, cacl2–nacl molten eutectic salt provided a liquid medium for the reaction of caco3 an...

Polyethylene glycol has been shown to bind to the molten globule intermediate on the bovine carbonic anhydrase B folding pathway. The mechanism of this interaction has been extensively probed. Polyethylene glycol (PEG) binds weakly to the molten globule first intermediate as measured by hydrophobic interaction chromatography, but PEG does not bind to either the native state or the second interm...

In the presence of macroscopic fibres of carbon nanotubes (CNT), various semicrystalline polymers are shown to present accelerated crystallisation through the formation of a transcrystalline (TC) layer perpendicular to the fibre axis. From differential scanning calorimetry, polarized optical microscopy and X-ray diffraction we establish this to be due to much faster nucleation rates at the fibr...

We explore the microfluidic generation of bubbles in a flow-focusing junction using a pressure-controlled device rather than the more common flow ratecontrolled devices. This device is a prototype for extending microfluidic drop generation methods to molten polymers. We show that the bubble generation process is highly sensitive to pressure: small changes in pressure induce large changes in bub...

Polymer crystals are metastable and exhibit morphological changes when being annealed. To observe morphological changes on molecular scales we started from small nanometer-sized crystals of highly folded long-chain polymers. Micron-sized stripes consisting of monolayers or stacks of several layers of flat-on oriented polyethylene nanocrystals were generated via evaporative dewetting from an aqu...