Natural sodium montmorillonite (NaMMT), Cloisite Na+ and two organophilic montmorillonites (OMMTs), Cloisites 20A and 15A were used. Polycaprolactone (PCL)/MMT composites containing 1, 3, 5, and 10 wt% of Cloisite Na+ and PCL/OMMT nanocomposites containing 5 and 10 wt% of Cloisites 20A and 15A were prepared via solution intercalation technique to study the influence of organic modifier loading ...

Plutonium (Pu) adsorption to and desorption from mineral phases plays a key role in controlling the environmental mobility of Pu. Here we assess whether the adsorption behavior of Pu at concentrations used in typical laboratory studies (≥10(-10) [Pu] ≤ 10(-6) M) are representative of adsorption behavior at concentrations measured in natural subsurface waters (generally <10(-12) M). Pu(V) sorpti...

Abs t rac t -The exchange reactions of Na, Ca and Mg on montmorillonite are revisited employing recently developed analytical and theoretical approaches. The fractional adsorption of the cations has been determined by displacing them from the adsorbed state in one step, using a low concentration of an organic cation of large binding affinity. The analysis of displaced and solution cations emplo...

A biased Monte Carlo method for the insertion of water in dense clay–water systems is presented. The use of this algorithm results in a considerable increase of the success rate of insertion attempts. It allows us to compute water adsorption isotherms up to high water densities, where the conventional Monte Carlo scheme fails. The isotherms were calculated by a combination of molecular dynamics...

Montmorillonite is an important layered phyllosilicate material with many useful physicochemical and mechanical properties, which widely used in medicine, environmental protection, construction industry, other fields. In order to a get better understanding of the behavior montmorillonite under high pressure, we studied its atomic structure, electronic properties using density functional theory ...

Manganese is an essential micronutrient for all organisms; however at high concentrations it has a toxic effect. Manganese toxicity is a serious constraint to crop cultivation since it is taken-up by plants and can easily be passed into the food chain again causing symptoms of Parkinson’s disease. A fully validated square-wave adsorptive cathodic stripping voltammetry method has been developed ...

The thermal properties such as specific heat capacity and heat dissipation of peloids play an important role in therapeutic applications. Therefore, these properties were determined on the peloids samples taken from spas where peloid applications are used in Turkey. In addition, some pure clay minerals were investigated to determine their suitability as possible constituents of therapeutic pelo...

An easy method was used to modify the Cloisite Na+ with different cationic surfactants. To prevent the damages in the clay crystal structure, the process was taken without acid activation. The organo-modified montmorillonite (MMT) were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), thermal analysis (TG/DTG), field emission scanning electron microscopy ...

-The effect of swelling on the b-dimension of Na-saturated, Upton, Wyoming montmorillonite was re-examined using powdered silicon as an internal standard. After being corrected with reference to the internal standard, the b-dimension did not increase through the entire range of swelling as reported previously. It increased up to a water content of ~ 3.0 g/g montmorillonite and remained constant...

The widely favored option for the safe storage of high-level radioactive waste is a multi-barrier disposal system with clay-based geotechnical barriers e.g. bentonite. Montmorillonite as major constituent bentonite (up to 90 wt.-%) an important sink potentially released radionuclides. adsorption 226Ra and Ba on Na-montmorillonite (SWy-2) was investigated function pH (edges) concentration (isoth...