A theory is presented for how magnetic nanostructures can catalyze intersystem crossing in molecular radical pairs. Magnetic field gradients near physically realistic nanostructures are strong enough to induce a relative reorientation of two electronic spins in <1 ns, overwhelming nuclear hyperfine coupling as a driver of intersystem crossing. Nanomagnetic control of intersystem crossing repres...

Abstract A Pd-Co bimetallic alloy encapsulated in melamine-based dendrimer supported on magnetic nanoparticles denoted as ?-Fe 2 O 3 @MBD/Pd-Co was synthesized by a facile co-complexation-reduction method and characterized sufficiently. The catalytic evaluation of showed promising results the Mizoroki–Heck Buchwald–Hartwig amination reactions various iodo-, bromo- challenging chloroarenes aqueo...

Summarization of electronic discussion fora is a unique challenge; techniques that work startlingly well on monolithic documents tend to fare poorly in this informal setting. Additionally, conventional techniques ignore much of the structures that have the potential to serve as valuable features in the summarization task. We present several novel examples of such features, including the catalys...