Increasing lithium content is shown to be a successful strategy for designing new cathode materials. In layered Li(x)Ni(2-4x/3)Sb(x/3)O2 (x = 1.00-1.15), lithium excess improves both discharge capacity and capacity retention at 1C. Structural studies reveal a complex nanostructure pattern of Li-Sb and Ni-Sb ordering where the interface between these domains forms the correct local configuration...

Needle-like ZnO nanostructures were synthesized by an organic-free hydrothermal process. Thehydrothermal synthesis was performed at very low pressure (~20 kPa) with duration of process only 10min. The products were characterized by X-ray powder diffraction (XRD)and transmission electronmicroscopy (TEM).The XRD pattern indicated that the needle –like ZnO nanostructures were hexag...

Ultra-small PbSe nanocrystals (NCs) were synthesized via a 'one-pot' approach in olive oil as the reaction medium and capping agent. The optical spectra showed discernible blue shifts in the absorption band edges (570-780 nm) due to strong quantum confinement effects and photoluminescence (PL) spectra showed significant strong emission peaks in the range of 780-850 nm. The broad peaks in the po...

We present a method to increase the stability of DNA nanostructure templates through conformal coating with a nanometer-thin protective inorganic oxide layer created using atomic layer deposition (ALD). DNA nanotubes and origami triangles were coated with ca. 2 nm to ca. 20 nm of Al2O3. Nanoscale features of the DNA nanostructures were preserved after the ALD coating and the patterns are resist...

Radiation-induced nanostructure formation is ubiquitous. It is routinely used in lithography employing photons and masks, or in the form of focused electron beams following a maskless approach for pattern definition in a radiation-sensitive resist, also commonly known as electron beam lithography. Examples of this are found in this Thematic Series covering the topics of selected-area silicon na...

Ultra-small PbSe nanocrystals (NCs) were synthesized via a ‘one-pot’ approach in olive oil as the reaction medium and capping agent. The optical spectra showed discernible blue shifts in the absorption band edges (570–780 nm) due to strong quantum confinement effects and photoluminescence (PL) spectra showed significant strong emission peaks in the range of 780–850 nm. The broad peaks in the po...

The mechanism of the formation of a self-aligned hydroxyapatite (HAP) nanocrystallite structure was examined. It is found that the highly ordered HAP nanocrystallite assembly is attributed to the so-called self-(homo)epitaxial nucleation and growth. On the other hand, according to this mechanism, a high supersaturation will give rise to a random assembly of HAP crystallites. The effects of ions...

The carbon nanostructure composed of an array of vertically aligned carbon nanotubes (CNTs) and a planar graphite layer (PGL) located at the top of the array has been obtained by the injection chemical vapor deposition method, realized using high temperature catalytic pyrolysis of xylene-ferrocene mixture. The carbon nature of the planar layer was identified using Auger electron spectroscopy. S...

A modified hydrothermal method was developed to synthesize ZnO-CuO composite nanostructures. A free-standing film made of ZnO-CuO nanostructures was assembled on the surface of the hydrothermal solution with a smooth surface on one side and a spherical surface on the other side. The structure, growth mechanism and the optical properties of the composite nanostructures were studied. Structural c...

We have developed a simple solid–vapor approach for controlled growth of the tetraleg ZnO nanostructure at high yield. The length of the tetraleg is 2–3 mm and the edge size of its centering nucleus is 70–200 nm. Our electron microscopy study gives the first direct evidence about the existence of the octahedral multiple twin nucleus, which is confirmed to be responsible for the formation of the...