In this research work, poly (acrylonitrile-butadienestyrene)/polypropylene (ABS/PP) blends were processed by melt compounding in a twin-screw extruder. Upgrading of the thermal characteristics of the obtained materials was attempted by the incorporation of organically modified montmorillonite (OMMT), as well as, by the addition of two types of compatibilizers; polypropylene grafted with maleic ...

Organoclays are sorbent materials prepared from clays by exchanging inorganic with organic cations. Their properties depend on the loading and conformational structure of the organic cations, but little information is available about the surface structures of organoclays. In this work, X-ray photoelectron spectroscopy (XPS) and classical molecular dynamics (MD) simulations are combined to chara...

Polymeric nanocomposites (PNC) are binary mixtures of strongly interacting, inorganic platelets dispersed in a polymeric matrix. For full exfoliation, the thermodynamic miscibility is required. There are three basic methods of organically-modified clay dispersion that might result in PNC: (1) in polymer solution (followed by solvent removal), (2) in a monomer (followed by polymerization), and (...

Linear polypropylene (PP)—composed of long polymer chains devoid of branches or crosslinked structure—and blends of PP with olefinic elastomers are widely used in the automotive and packaging industries. What makes foams produced with these materials of growing interest is their potential to replace the prevalent thermoset polyurethane foams which are not recyclable. However, the production of ...

Polymer nanocomposites with organically modified nanoclay have two different types of interface sites: edges with hydroxyl groups and gallery faces with oxygen atoms. In this study, the polymer-particle interface was strengthened by a coupling agent, aminoalkyldimethoxysilane, which allowed the formation of covalent bonds between silane treated organoclay and maleic anhydride groups of the long...

(2006) Changes in the morphology of organoclays with HDTMA+ surfactant loading. Abstract The detailed understanding of the interlayer structure of organoclays is of importance in the design of organoclay based materials and their industrial applications. In this study, Transmission Electron Microscopy (TEM), Scanning Electron Microscopy (SEM) and X-Ray Diffraction (XRD) have been used to provid...

The combination of Ethylene-vinyl acetate copolymer (EVA) with nanoclay has wide commercial applications (such as packaging films and cables), which depend on the vinyl acetate contained in the main chain. As the vinyl acetate content increases, the copolymer presents less crystallinity and different mechanical behavior. EVA with 40 wt% vinyl acetate content (EVA40)/ organoclay nanocomposites w...