نتایج جستجو برای: perchloric acidfunctionalized silica nanosphere

تعداد نتایج: 38929  

Journal: :Mongolian journal of chemistry 2022

In developed countries, nanoparticles derived from natural minerals and high-purity chemicals both are widely studied, while in developing countries like Mongolia, the minerals-based have more interest because of low production cost applicability domestic for their production. For synthesis mineral-based nanomaterials, it is important first to define chemical composition physical structure loca...

Journal: :Investigative ophthalmology & visual science 2012
Rahul Garhwal Sally F Shady Edward J Ellis Jeanne Y Ellis Charles D Leahy Stephen P McCarthy Kathryn S Crawford Peter Gaines

PURPOSE To formulate conventional contact lenses that incorporate nanosphere-encapsulated antibiotic and demonstrate that the lenses provide for sustained antibacterial activity. METHODS A copolymer composed of pullulan and polycaprolactone (PCL) was used to synthesize core-shell nanospheres that encapsulated ciprofloxacin. Bactericidal activity of the nanosphere-encapsulated ciprofloxacin (n...

Journal: :Nature communications 2013
Alexander Gumennik Lei Wei Guillaume Lestoquoy Alexander M Stolyarov Xiaoting Jia Paul H Rekemeyer Matthew J Smith Xiangdong Liang Benjamin J-B Grena Steven G Johnson Silvija Gradečak Ayman F Abouraddy John D Joannopoulos Yoel Fink

The ability to produce small scale, crystalline silicon spheres is of significant technological and scientific importance, yet scalable methods for doing so have remained elusive. Here we demonstrate a silicon nanosphere fabrication process based on an optical fibre drawing technique. A silica-cladded silicon-core fibre with diameters down to 340 nm is continuously fed into a flame defining an ...

Journal: :Journal of the American Chemical Society 2009
Juan L Vivero-Escoto Igor I Slowing Chian-Wen Wu Victor S-Y Lin

A gold nanoparticle (AuNP)-capped mesoporous silica nanosphere (MSN)-based intracellular drug delivery system (PR-AuNPs-MSN) for the photoinduced controlled release of an anticancer drug, paclitaxel, inside of human fibroblast and liver cells was synthesized and characterized. We found that the mesopores of MSN could be efficiently capped by the photoresponsive AuNPs without leaking the toxic d...

Journal: :Langmuir : the ACS journal of surfaces and colloids 2013
Shuru Li Xuan Jiao Hengquan Yang

Inspired by the structure features of micelle, we attempt to synthesize a novel functionalized mesoporous silica nanosphere consisting of a hydrophobic core and a hydrophilic shell. The obtained solid materials were structurally confirmed by N(2) sorption, X-ray diffraction (XRD), and transmission electron microscopy (TEM). Their compositions were characterized by Fourier transfer infrared spec...

Journal: :Analytical chemistry 2009
Christa L Brosseau Alessa Gambardella Francesca Casadio Cecily M Grzywacz Jan Wouters Richard P Van Duyne

Tailored ad-hoc methods must be developed for successful identification of minute amounts of natural dyes on works of art using Surface-Enhanced Raman Spectroscopy (SERS). This article details two of these successful approaches using silver film over nanosphere (AgFON) substrates and silica gel coupled with citrate-reduced Ag colloids. The latter substrate functions as the test system for the c...

The rate of hydrolysis of trans -[Cr(NH ) F ] was obtained as a function of acid concentsation in perchloric, sulfuric and nitric acid at 3Q°C. The results have been analyzed by the treatment of Bunnett and Olsen. Values of the parameter ?in Olsen equation are consistent with the participation of water as a proton-wansfer agent in the rate-determining step. The Arrhenius plot for perchlori...

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