introduction blue light is a part of the spectrum with the highest energy content, which can reach the retina. the damage that it can cause to the retina is called photochemical or blue-light retinal injury. for the retinal injury assessment of the photochemical and aphakic retinal hazards in the wavelength range of 300-700 nm, use of effective spectral radiance limits (w.m-2.sr-1) seems to be ...

The photosensitivity of metal carbonyls has been known almost as long as the class of coordination compounds itself. Among no other group of inorganic compounds may one find so many light-sensitive materials. Hence photochemical reactions of metal carbonyls have found wide applications for synthetic purposes. However, whereas much research has been done to understand the thermal reactions," the...

New and simple protocols are described for the conversion of the enzymatically-derived and enantiomerically pure cis-1,2-dihydrocatechol (X = I) and its 6-methylated derivative into either antipodal form of compounds embodying the tricyclic frameworks of terpenoids . Key steps include intramolecular Diels-Alder (IMDA) and (in some cases) singlet or triplet-based photochemical processes.

We present the essential dynmnic model of the •nesospheric photochemical system (PCS) •'md suggest a step-by-step procedure for elaborating such a model of an arbitrary atmospheric PCS. The model demonstrates the same possibilities ofnonlinear dynamic behavior and qualitatively the same dynamic haracteristics a the corresponding original model, but is much simpler than the latter. We show the a...

As an important precursor of hydroxyl radical, nitrous acid (HONO) plays a key role in the chemistry of the lower atmosphere. Recent atmospheric measurements and model calculations show strong enhancement for HONO formation during daytime, while they are inconsistent with the known sources in the atmosphere, suggesting that current models are lacking important sources for HONO. In this article,...

Halogens produced by ocean biological and photochemical processes reach the tropical tropopause layer (TTL), where cold temperatures and the prevailing low ozone abundances favor the diurnal photochemical enhancement of halogen atoms. Under these conditions atomic bromine and iodine are modeled to be the dominant inorganic halogen species in the sunlit TTL, surpassing the abundance of the commo...

Historically photochemical mechanisms and air quality models have been evaluated primarily in terms of there ability to simulate observed O3 data. There is an increasing awareness that mechanism and models must also be evaluated in terms of their ability to simulate the fundamental chemical processes that control O3 formation and the sensitivity of O3 to emissions reductions (Arnold et al., 199...