ion of H2 + by O occurs with 55% yield to produce the desired CCl2 ; however, CHCl2 produced by proton abstraction, with m/z only 1 amu greater than the desired product, is a significant minor ionic reaction product. Since theWien filter has a mass resolution of at bestm/DmE 40, we can only partially separate ions within 1 amu of each other at m/z E 80, specifically CCl2 and CHCl2 . It was init...

Hollow polyhedra and cubes of nanostructured Cu(2)O particles have been synthesized by reduction of CuSO(4) with ascorbate acid in the solution phase. The nanostructures were obtained when the cetyltrimethylammonium (CTAB) concentration ranged from 0 to 0.03 M in the presence of NaOH. Structural characterizations, by means of x-ray photoelectron spectroscopy (XPS) for measuring Cu valence state...

The photoelectron spectrum of the 7,7,8,8-tetracyanoquinodimethane (TCNQ) radical anion has been measured at 3.1 eV. Additionally, the ultrafast relaxation dynamics of the first excited state (1(2)B(3u)) of TCNQ(-) have been studied using time-resolved photoelectron spectroscopy, which reveals that it undergoes internal conversion back to the ground state ((2)B(2g)) with an associated lifetime ...

We report high-resolution anion photoelectron spectra of thiozonide (S3(-)) acquired by slow electron velocity-map imaging (SEVI). The ions were cryogenically cooled within an ion trap before photodetachment. We measure an electron affinity of 2.3630(9) eV, resolving discrepancies in previously reported photoelectron spectra that resulted from the presence of vibrational hot bands. The SEVI spe...

The highest resolution vacuum ultraviolet photoabsorption spectrum of ethyl formate, C2H5OCHO, yet reported is presented over the wavelength range 115.0-275.5 nm (10.75-4.5 eV) revealing several new spectral features. Valence and Rydberg transitions and their associated vibronic series, observed in the photoabsorption spectrum, have been assigned in accordance with new ab initio calculations of...

We report the photoelectron spectrum of anionic N-acetylproline, (N-AcPro)(-), measured with 3.49 eV photons. This spectrum, which consists of a band centered at an electron binding energy of 1.4 eV and a higher energy spectral tail, confirms that N-acetylproline forms a valence anion in the gas phase. The neutrals and anions of N-AcPro were also studied computationally at the B3LYP∕6-31++G(d,p...

Molybdenum oxides have been widely investigated for their broad applications ranging from electronics to energy storage. Photodetectors based on molybdenum trioxide (MoO3), however, were seldom reported owing to their low conductivity and weak photoresponse. Herein we report a photodetector based on single MoO3 nanobelt with wide visible spectrum response by introducing substantial gap states v...

The first ab initio calculations of the vertical excitation energies and oscillator strengths are presented for the neutral electronic transitions of methyl formate, C(2)H(4)O(2). The highest resolution VUV photoabsorption spectrum of the molecule yet reported is presented over the wavelength range 115 to 310 nm (10.8 to 4.0 eV) revealing several new spectral features. Valence and Rydberg trans...

The pre-peak in the x-ray-absorption near-edge structure ~XANES! of CuFeS2 is studied by exploring the associated photoelectron probability density as well as by investigating the cluster size effect. All significant features of the Cu, Fe, and S K-edge experimental spectra and of the S L2,3-edge spectrum are successfully reproduced by the real-space multiple-scattering ~RSMS! calculations with...

Pump-probe photoionization has been used to map the relaxation processes taking place from highly vibrationally excited levels of the S(2) state of azulene, populated directly or via internal conversion from the S(4) state. Photoelectron spectra obtained by 1+2(') two-color time-resolved photoelectron imaging are invariant (apart from in intensity) to the pump-probe time delay and to the pump w...