Time-resolved fluorescence data was collected from a series of 23 bulk crude petroleum oils and six microscopic hydrocarbon-bearing fluid inclusions (HCFI). The data was collected using a diode laser fluorescence lifetime microscope (DLFLM) over the 460-700 nm spectral range using a 405 nm excitation source. The correlation between intensity averaged lifetimes (tau) and chemical and physical pa...

Fluorescence anisotropy measurements reveal a non-monotonic density dependence for average rotation time (τ(R)) of a polar solute, coumarin153 (C153) in polar supercritical fluoroform (CHF(3)). The conventional Stokes-Einstein-Debye model, relating τ(R) to the solvent viscosity, fails to explain the observed density dependence, because the experimental viscosity increases monotonously with dens...

In this study, the effect of thermal radiation on micro-polar fluid flow over a wavy surface is studied. The optically thick limit approximation for the radiation flux is assumed. Prandtl’s transposition theorem is used to stretch the ordinary coordinate system in certain directions. The wavy surface can be transferred into a calculable plane coordinate system. The governing equations of micro-...

Supercritical fluid extraction systems can be configured in a number of different ways and the operating conditions can span the full continuum of temperatures and pressures. Every combination presents differing solubilities and mass transfer behaviour and results in different cost. Optimal conditions for processing are rarely coincident with optimal conditions for maximum solubility. For a typ...

2014 Through the description of three new series of polar compounds with a cyano or a nitro terminal group we progress in the generalization of the (x, T) binary diagrams dealing with bilayered fluid smectic phases. New arguments are put forward concerning the conspicuousness of the SAd-S A2 transition according to the structure of the SAd phase. For the second time a SA2~ SC2~ S? bilayer seque...

This article reports results from numerical simulations of the gravitational radiation emitted from nonrotating relativistic stars as a result of the axisymmetric accretion of layers of perfect fluid matter, shaped in the form of quadrupolar shells. We adopt a hybrid procedure where we evolve numerically the polar nonspherical perturbations equations of the star coupled to a fully nonlinear hyd...

Pressure drop of fully developed, laminar, incompressible flow in smooth mini and microchannels of arbitrary cross-section is investigated. A compact approximate model is proposed that predicts the pressure drop for a wide variety of shapes. The model is only a function of geometrical parameters of the cross-section, i.e., area, perimeter, and polar moment of inertia. The proposed model is comp...

The isotropic (14)N-hyperfine coupling constant, a(o)(N), of nitroxide spin labels is dependent on the local environmental polarity. The dependence of a(o)(N) in fluid phospholipid bilayer membranes on the C-atom position, n, of the nitroxide in the sn-2 chain of a spin-labeled diacyl glycerophospholipid therefore determines the transmembrane polarity profile. The polarity variation in phosphol...

In the present work a two fluid model for blood flow through abnormally constricted human artery (stenosed artery) has been developed. The model consists of a core region of suspension of all erythrocytes assumed to be micro-polar fluid so as to include the micro-structural effects in addition to the peripheral-layer viscosity effects, and a peripheral plasma layer free from cells of any kind o...