We present simulations of aqueous polyelectrolyte complexes with new MARTINI models for the charged polymers poly(styrene sulfonate) and poly(diallyldimethylammonium). Our coarse-grained polyelectrolyte models allow us to study large length and long time scales with regard to chemical details and thermodynamic properties. The results are compared to the outcomes of previous atomistic molecular ...

The build up of polyelectrolyte multilayers (PEMs) was observed by a silicon-on-insulator (SOI) based thin film resistor. Differently charged polyelectrolytes adsorbing to the sensor surface result in defined potential shifts, which decrease with the number of layers deposited. We model the response of the device assuming electrostatic screening of polyelectrolyte charges by mobile ions within ...

The overall goal of this thesis was to exploit the versatility of the polyelectrolyte multilayer (PEM) to fabricate a novel micro/nanofluidic device for patterning bacteria in BioMEMS. Nanofluidic channels offer new opportunities for advanced biomolecule manipulation and separation science because they provide unique capabilities such as ion-permselectivity and nanometer-sized structures. In or...

Neutron reflectivity measurements were performed on a cell membrane mimic system consisting of a polyelectrolyte multilayer plus a synthetic terpolymer plus a phospholipid layer, at all of the intermediate steps in the assembly of the composite, to obtain neutron scattering length density depth profiles. The polyelectrolyte multilayer functions as a soft, water-containing cushion for the membra...

............................................................................... 10 LIST OF PAPERS ......................................................................... 12 INTRODUCTION ......................................................................... 14 Background and aim ............................................................................ 14 The mucous gel and mucins ..........

A novel, magnetic silica sorbent with polyelectrolyte multilayers (PEMs) on its surface was prepared, and was used for Magnetic Solid Phase Extraction (MSPE) of trace A+ via Flame Atomic Absorption Spectrometry (FAAS). The experimental parameters for the MSPE procedure, such as the pH, type, and concentration of eluent, ultrasonic time and effects of co-existing ions wer...

In polyelectrolyte multilayer (PEM) films assembled from poly(diallyldimethylammonium chloride) and poly(styrene sulfonate) via the layer-by-layer deposition technique, the counterions were exchanged with silver ions, which were subsequently reduced in situ to produce silver (Ag) nanoparticles. The Ag nanoparticles embedded in the PEMs were found to undergo an interesting coarsening process ove...