Different regioisomeric and diastereomeric isosorbide mono-epoxides are prepared polymerized to thermally stable relatively rigid biobased linear polyethers.

We show that a network of quenched random grain boundaries, terminating in poly-merized patches containing excess disclinations, destabilizes the at phase of sparsely poly-merized membranes, in contrast to membranes completely polymerized in the liquid state. We argue that many of these grain boundaries will buckle, even in the absence of excess disclinity, leading to a glassy wrinkled phase co...

background and aims. the aim of this study was to evaluate the effect of dilution and curing methods of an etch-and-rinse adhesive and a self-etching primer from the same manufacturer at early exposure time on cytotoxicity of primary hu-man gingival fibroblasts. materials and methods. primary human gingival fibroblasts were exposed to different dilutions of adper single bond (asb) and adper pro...

Multiphoton polymerization (MPP) enables 3D fabrication of micro- and nanoscale devices with complex geometries. Using MPP, we create a 3D platform for protein assays. Elevating the protein-binding sites above the substrate surface allows an optically sectioned readout, minimizing the inevitable background signal from nonspecific protein adsorption at the substrate surface. Two fluorescence-lin...

Polyethylene glycol (PEG) grafting has a great potential to create nonfouling and nonthrombogenic surfaces, but present techniques lack versatility and stability. The present work aimed to develop a versatile PEG grafting method applicable to most biomaterial surfaces, by taking advantage of novel primary amine-rich plasma-polymerized coatings. Star-shaped PEG covalent binding was studied using...

The polymerization of elongated micellar structures offers a novel approach to the production of high-aspect-ratio, water-soluble amphiphilic nanorods. A cationic surfactant with a vinyl-containing counterion, cetyltrimethylammonium 4-vinylbenzoate, has been synthesized and polymerized to produce high-aspect-ratio nanoparticles which are insensitive to changes in solution conditions. Aggregates...

statement of problem: fracture strength of a denture base resin is of great concern, and many approaches have been used to strengthen acrylic resin dentures. purpose: the aim of this study was to measure the transverse strength of a heat polymerized acrylic resin, after reinforcement with metal wire and two types of glass fibers. materials and methods: forty rectangular specimens (65.0×10.0×3.3...

Interactions between the cell and the extracellular matrix regulate a variety of cellular properties and functions, including cellular rheology. In the present study of cellular adhesion, area was controlled by confining NIH 3T3 fibroblast cells to circular micropatterned islands of defined size. The shear moduli of cells adhering to islands of well defined geometry, as measured by magnetic mic...