a new model based on a combination of the polymeric multigrain and multilayer models has been developed to predict the polymerization rate, particle growth, morphology, effective parameters on broadening of the molecular weight distribution, number and weight average of the molecular weight, isotacticity index and bulk density of polymer. mathematical correlations and the kinetics used in this ...

A study was conducted into the potential of ultrasound as a qualitative and quantitative tool for the Magnetic Density Separator (MDS), where an ultrasound sensor array will operate from inside the MDS ferrofluid. The desired applications of the ultrasound are monitoring of polyolefin particles in flow during the separation process, and performing throughput measurements and quality inspection....

We report here the synthesis of a novel electroactive polyolefin and demonstrate through a combination of SEC-MALS and DLS how this type of functional polymer can be folded in a controlled fashion from an expanded coil to a tightly wound globule using sequentially activated noncovalent and covalent intra-chain interactions.

The ability to predict polymer properties from a knowledge of the chemical architecture of the chains is one of the main goals of polymer science, and achievement of this can be very useful in the development of new polymeric materials. In this paper the connection between dimensions of polyolefin chains and some of their most fundamental properties, such as the degree of entanglement and misci...

This study presents a study on the ductility performance of hybrid fibre reinforced concrete. The influence of fibre content on the ductility performance of hybrid fibre reinforced concrete specimens having different fibre volume fractions was investigated. The parameters of investigation included modulus of rupture, ultimate load, service load, ultimate and service load deflection, crack width...

The large variation in miscibility of blends of polyolefins is related to the architecture of the chain molecules. In this paper we present first results of an approach in which small scale simulations of local interactions are combined with an analytical model for the thermodynamics, the Born-Green-Yvon lattice model, to predict phase diagrams of polyolefin blends from the pure component prope...

An investigation of Thapsia garganica afforded a series of tetracyclic C-19 dilactones, whose production was dependent on the time and location of the collection. These unusual tetrahomosesquiterpenoids are presumably biosynthesized via a carbon dioxide-triggered electrophilic polyolefin cyclization. Despite the structural differences with thapsigargin, these compounds showed SERCA-inhibiting p...

We present a theoretical approach which maps polymer blends onto mixtures of soft-colloidal particles. The analytical mesoscale pair correlation functions reproduce well data from united atom molecular dynamics simulations of polyolefin mixtures without fitting parameters. The theory exactly recovers the analytical expressions for density and concentration fluctuation structure factors of soft-...

As a significant part of municipal solid waste (MSW), waste cardboard (CB) is a sustainable, inexpensive, and rich source of cellulose. Previous studies of polyolefin/CB composites have reported modest enhancement to major reduction in modulus and major reduction in elongation at break values relative to neat polymer. Here, green hybrids of low density polyethylene (LDPE) and polypropylene (PP)...

Introduction Olefin polymers are the most widely used materials in the plastics industry today. To optimize their properties and processibility, blending is often used. This is particularly important for the metallocene-catalyst based polyolefins. By altering certain shear-thinning and strain-hardening characteristics, blending can enhance the processibility of the material. This is in addition...