A facile approach composed of hydrothermal process and annealing treatment is proposed to directly grow cobalt-manganese composite oxide ((Co,Mn)3O4) nanostructures on three-dimensional (3D) conductive nickel (Ni) foam for a supercapacitor electrode. The as-fabricated porous electrode exhibits excellent rate capability and high specific capacitance of 840.2 F g(-1) at the current density of 10 ...

An analytical expression is presented for the voltage response including the transient voltage for a simple ~i.e., no concentration gradients! porous electrode model subject to a sinusoidal input current density. The transient voltage response as a function of the frequency, exchange current density, and double layer capacitance is studied independent of the periodic ~steady state! voltage resp...

From measurements using stationary and rotating disc and ring-disc electrodes, it is concluded that the reduction reactions of the divalent methylviologen cation MV 2(to MV +" and MV °) proceed via the conduction band of both porous and crystalline silicon. The product of the second reduction step (MV °) forms a blocking layer on the electrode. The oxidation reactions of MV ° and MV ÷" take pla...

A strong correlation exists between the performance of Solid Oxide Cells (SOCs), working either in fuel cell or electrolysis mode, and their electrodes microstructure. However, the basic relationships between the three-dimensional characteristics of the microstructure and the electrode properties are not still precisely understood. Thus, several studies have been recently proposed in an attempt...

MnO2/carbon nanotube [CNT] nanocomposites with a CNT core/porous MnO2 sheath hierarchy architecture are synthesized by a simple hydrothermal treatment. X-ray diffraction and Raman spectroscopy analyses reveal that birnessite-type MnO2 is produced through the hydrothermal synthesis. Morphological characterization reveals that three-dimensional hierarchy architecture is built with a highly porous...

In this approach, electro-oxidation of a mixture of uric acid and ascorbic acid at the surface of tosyl surface carbon nanoparticles/glassy carbon electrode has been performed. The electro-oxidation of these compounds at bare electrode is sluggish and there is no suitable peak separation between them. However, using functionalized carbon nanoparticles, two well-defined anodic peaks with a consi...