An iodide ion-selective PVC membrane sensor based on copper (Π)-bis-Nphenilsalicyldenaminatocomplex as a novel sensing material is successfully developed. Theelectrode showed a good selectivity for iodide ion with respect to common inorganic anions. Thesensor exhibited a good linear response with slope of _58.6 ± 0.4 mV per decade over theconcentration range of 5.0 × 10-6 to 1.0 × 10-1 mol L-1,...

Potentiometric sensor based on commercial pencil graphite electrodes coated with polyaniline (PAni) composite with Eosin Y (EY) termed as PGE/PAni-EY have been developed for potentiometric determination of silver ion. The electrode exhibited linear response with Nernstian slope of 57.6±0.8 mV per decade within the range of 1.0×10 to 1.0×10 M with limit of detection 6.5×10 M silver ion. Fast and...

The advent of ion-selective electrodes made possible the potentiometry of sodium in serum and plasma. These methods were based on dilution of serum, as done in flame photometry, and the results were identical. Analysis of whole blood precludes dilution and so "direct" potentiometry was developed. Results by this technique are variable but tend to compensate for the spurious hyponatremias found ...

A rapid and simple sequential potentiometric method is described for the determination of nitrate and chloride ions in vegetables, by using home-made ion selective electrodes. The extraction of both ions from the vegetable samples was effected by magnetic stirring of the samples during 30 min in water at room temperature. Direct Potentiometry was used as analytical technique for measurement. Th...

A PVC membrane Ni(II) ion selective electrode has been constructed using (1E,2E)-bis(2-aminophenyl)N'1,N'2-dihydroxyethanebis as membrane carrier. The electrode exhibited a goodpotentiometric response for Ni(II) over a wide concentration range 1.0×10-4 to 1.0×10-1M with aslope of 29.4±0.5 mV/decade a and a working pH range of 6.5-9.0. It had a fast response time of≤20s. The best performance was...

A PVC ion-selective membrane electrode based on Cd-tetraphenyl porphyrine as a carrier was prepared fordetermination of MnO4- ion. This electrode revealed good selectivity toward permanganate ion over a widevariety of anions. Effects of some experimental parameters such as nature of the plasticizer, the amounts ofcarrier and additive, and concentration of the internal solution on the potential ...

Abstract The application of polyaniline nanofibers doped with chloride and nitrate ions (PANINFs-Cl PANINFs-NO 3 ) in potentiometry was described. Both kinds were used as an ion-to-electron transducer ion-selective electrodes solid contact (SCISEs). Extensive research on the properties themselves (SEM, UV–Vis spectroscopy, FTIR) constructed (potentiometric methods, electrochemical impedance spe...

a new cesium ion selective pvc membrane based on parent calix [4] arene was developed for potentiometric determination of cesium in environmental samples. the electrode based on p-5,11,17,23tetra(tertbutyl) 25,26,27,28-tetrahydroxy calix[4]arene(thc) as ionophor ,dibutyl phthalate (dbp)as plasticizer ,sodium tetra phenyl borate(natpb)and oleic acid as lipophilic salt and additive showed the bes...