A self-assembled supramolecular metallacyclic rectangle was investigated with scanning tunneling microscopy on highly oriented pyrolytic graphite and Au(111) surfaces. The rectangles spontaneously adsorb on both surfaces and self-organize into well ordered adlayers. On highly oriented pyrolytic graphite, the long edge of the rectangle stands on the surface, forming a 2D molecular network. In co...

Macroscopic concentration of massless charge carriers with linear conic spectrum Dirac Fermions (DF) was shown in 2004 to exist in Highly Oriented Pyrolytic Graphite (HOPG) and governs its electronic properties. These carriers can have the same nature as DF observed in graphite monolayer (Graphene) and let to view HOPG as superposition of 2D carbon layers, almost independent electronically. We ...

Glucose sensing electrodes have been realized by immobilizing glucose oxidase (GOx) on unmodified edge plane of highly oriented pyrolytic graphite (epHOPG) and the native oxide of heavily doped silicon (SiO2/Si). Both kinds of electrode show direct interfacial electron transfer due to the redox process of the immobilized GOx. The measured formal potential of the redox process agrees with that o...

Recent publications demonstrated the generation of magnetic order at room temperature on graphite surfaces after irradiation with protons. In this contribution we show that it is possible to produce magnetic structures in the micrometer range using a proton micro-beam by proton irradiation of the surface of highly oriented pyrolytic graphite samples. The experimental results are compared with m...

The firstand second-order Raman spectral features of graphite and related sp2 carbon materials were examined with laser wavelengths ranging from 293 to 1064 nm. A wide range of carbon materials was considered, including highly ordered pyrolytic graphite (HOPG), powdered and randomly oriented graphite, and glassy carbon prepared at different heat-treatment temperatures. Of particular interest is...

We report on spectroscopic study of pyrolytic hBN (pBN) by means of time-and energy-resolved photoluminescence methods. A high purity of pBN samples (though low crystallinity) allows complementary information about excited states involved into the luminescence process. We affirm our recent conclusions about the impurity-related nature of most of the fluorescence bands in microcrystalline hBN. I...

Microwave-assisted heating method is used to treat graphite oxide (GO), pyrolytic graphene oxide (PGO) and hydrogen-reduced pyrolytic graphene oxide (HPGO). Pure or doped graphene are prepared in the time of minutes and a thermal deoxygenization reduction mechanism is proposed to understand their microwave adsorption behaviors. These carbon materials are excellent catalysts in the reduction of ...