Abstract Chemical gardens, which are self‐organizing, abiotic, inorganic precipitates in far‐from‐equilibrium systems, of interest for prebiotic chemistry/origin life research and, under certain reaction can be considered hydrothermal vent analogs. While the presence different additives to chemical including phosphate and amino acids, have been explored, reactivity organic molecules garden syst...

Carbonaceous meteorites deliver a variety of organic compounds to Earth that may have played a role in the origin and/or evolution of biochemical pathways. Some apparently ancient and critical metabolic processes require several compounds, some of which are relatively labile such as keto acids. Therefore, a prebiotic setting for any such individual process would have required either a continuou...

Pyruvic acid is an organic compound used in various fields (e.g., the pharmaceutical, cosmetic, food, and chemical industries) subject to constantly growing demand. liquid at room temperature, rendering manipulation less straightforward. Furthermore, phase, pyruvic air-sensitive. We here present a multi-component crystal engineering strategy render solid under ambient conditions, focusing on co...

Greenhouse grown seedlings of corn (Zea mays L.) and foxtail (Setaria faberii Herrm.) were used as source material in determining the intracellular localization of nitrate reductase, nitrite reductase, and glutamic acid dehydrogenase, Nonaqueous and aqueous isolation techniques were used to establish that nitrite reductase is localized within the chloroplasts, but that nitrate reductase and glu...

This enzymatic method for determination of sialic acid involves use of neuraminidase (EC 3.2.1.18), N-acetylneuraminate lyase (EC 4.1.3.3), acylglucosamine 2-epimerase (EC 5.1.3.8), N-acetylhexosamine oxidase (from Pseudomonas sp.), and peroxidase (EC 1.11.1.7). Because the method does not require pyruvic acid in the assay medium, interference by pyruvic acid in serum can be avoided. This simpl...

The study of organic chemistry in atmospheric aerosols and cloud formation is of interest in predictions of air quality and climate change. It is now known that aqueous phase chemistry is important in the formation of secondary organic aerosols. Here, the photoreactivity of pyruvic acid (PA; CH3COCOOH) is investigated in aqueous environments characteristic of atmospheric aerosols. PA is current...

The hydrogen reacts with lactic acid to form propionic acid. Pyruvic acid has been isolated from the fermentation of glucose (1934) and of lactic acid (unpublished data) by Wood and Werkman. These investigators supported Van Niel's proposed dissimilation of pyruvic acid inasmuch as the occurrence of acetaldehyde could not be demonstrated. Little information is available concerning the aerobic d...

The synthetic route in this work is based on the classical Friedel-Crafts strategy, and began with 1,4-dimethoxybenzene (I), followed by alkylation and selective demethylation of 2-methoxy function in 0x0-acid (3). The orthoformylation to synthesize aldehyde (6) was based on the Reimer-Tieman reaction. Chain extension of this aldehyde required methylation of the hydroxyl group and condensat...