High-level ab initio calculations are performed on the coinage metal cations (Cu+, Ag+, and Au+) interacting with each of the rare gases [Rg (Rg=He to Rn)]. The RCCSD(T) procedure is employed, with basis sets being of approximately quintuple-zeta quality, but with the heavier species using relativistic effective core potentials. The interaction potentials are compared to experimental and theore...

The separation of molecules with similar size and shape is an important technological challenge. For example, rare gases can pose either an economic opportunity or an environmental hazard and there is a need to separate these spherical molecules selectively at low concentrations in air. Likewise, chiral molecules are important building blocks for pharmaceuticals, but chiral enantiomers, by defi...

für Naturforschung in cooperation with the Max Planck Society for the Advancement of Science under a Creative Commons Attribution 4.0 International License. Dieses Werk wurde im Jahr 2013 vom Verlag Zeitschrift für Naturforschung in Zusammenarbeit mit der Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. digitalisiert und unter folgender Lizenz veröffentlicht: Creative Commons Namen...

For transverse profile determination a non-intercepting Beam Induced Fluorescence (BIF)-monitor was developed. The BIF-monitor detects fluorescence light emitted by residual gas molecules after atomic collisions with beam ions [1]. Using an imaging spectrograph the spectral response was mapped and associated with the corresponding gas transitions in helium, argon, krypton, xenon and nitrogen. S...

Results of a semirelativistic R-matrix calculation are compared with experimental values for light polarizations and alignment parameters of the second excited-state manifolds of neon and krypton following electron impact excitation. The calculations focus on the near-threshold regime, where negative-ion resonances have a significant effect on the atomic alignment. A grouping of the alignment v...