A simple single-stage approach, based on the hydrothermal technique, has been introduced to synthesize reduced graphene oxide/titanium dioxide nanocomposites. The titanium dioxide nanoparticles are formed at the same time as the graphene oxide is reduced to graphene. The triethanolamine used in the process has two roles. It acts as a reducing agent for the graphene oxide as well as a capping ag...

Titanium dioxide and copper oxide nanoparticles are more and more widely used because of their catalytic properties, of their light absorbing properties (titanium dioxide) or of their biocidal properties (copper oxide), increasing the risk of adverse health effects. In this frame, the responses of mouse macrophages were studied. Both proteomic and targeted analyses were performed to investigate...

Titanium dioxide has been proven for toxicity by in vitro and in vivo approaches, however, further studies are needed in nano-toxicological research using in silico analysis. In this study, Autodock 4.0.5 was used in an attempt to evaluate the interaction of titanium dioxide with proteins. Different cellular proteins were sorted to study the interaction, binding sites, and active sites as a poc...

For TiO2 photocatalysts, recombination of photoexcited electrons and holes would occur in crystalline defects such as oxygen vacancies, Ti ions, and surface states. Therefore, it is believed that the density of crystalline defects should be decreased to improve the photocatalytic activity of TiO2 particles. Contrary to this common knowledge, the introduction of crystalline defects by hydrogen r...

Titanium dioxide nanopowders doped with different amounts of Fe ions were prepared by coprecipitation method. Obtained materials were characterized by structural (XRD), morphological (TEM and SEM), optical (UV/vis reflection and photoluminescence, and Raman), and analytical techniques (XPS and ICP-OES). XRD analysis revealed rutile crystalline phase for doped and undoped titanium dioxide obtain...

Nanocrystals of Titanium dioxide were prepared via sol-gel and solvothermal method. They were characterized by X-ray diffraction and Scanning Electron Microscopy studies. The anatase and rutile phase reflections of the Titanium dioxide nanocrystals were identified by X-ray diffraction data. The micro strain value of the nanocrystals were analysed by W-H plot method. Very small value of micro st...

Biological studies of two titanium dioxide polymorphs, rutile and anatase, have produced conflicting results. Generally, the in vivo and in vitro methods used to evaluate pneumoconiotic dusts have shown the polymorphs to be inert, but occasionally both minerals have been reported to produce effects consistent with biologically active minerals. Many of these reports failed to specify which polym...

catalytic and photocatalytic reactions of (2-chloroethyl) phenyl sulfide (2-ceps), a mimic of bis (2-chloroethyl)  sulfide (i.e. sulfur mustard) were studied on the surfaces of titanium oxide. tio2 nanoparticles (anatase, rutile and mixture of 80% anatase/20% rutile) along with bulk tio2 were tested as reactive sorbents for reaction of 2-ceps at room temperature (25±0.5°c). reactions were monit...

A vicinal rutile TiO2(110) crystal with a smooth variation of atomic steps parallel to the [1-10] direction was analyzed locally with STM and ARPES. The step edge morphology changes across the samples, from [1-11] zigzag faceting to straight [1-10] steps. A step-bunching phase is attributed to an optimal (110) terrace width, where all bridge-bonded O atom vacancies (Obr vacs) vanish. The [1-10]...

The interest to nanoobjects is mainly attracted by the fact that their properties (and also biological in particular interest to the project) differ drastically from the properties of either bulk material or constituent molecules. The fundamental task is correlation between structure of the nanoparticles and their interaction with surrounding media. The aim of project is a study of interaction ...