The authors conducted a population-based case-control study of 1,068 incident leukemia cases and 5,039 controls aged 20–74 years during 1994–1997 to examine the association between exposure to drinking water chlorination disinfection by-products and adult leukemia risk in Canada. Residence and drinking water source histories and data from municipal water supplies were used to estimate individua...

Electron-rich aromatic C-H bonds undergo regioselective chlorination and bromination in the presence of CuX(2), LiX (X = Cl, Br) and molecular oxygen. Preliminary mechanistic insights suggest that the bromination and chlorination reactions proceed by different pathways.

Chlorination-elimination chemistry coupled with three-component Joullié-Ugi reaction and facile deprotection allowed efficient access to an array of polyhydroxylated pyrrolidines through parallel synthesis that may be considered to be a library of imino (aza) sugars (glycomimetics) and/or dihydroxyprolyl peptides (peptidomimetics). The utility of generating such a library was illustrated by scr...

shortage of water has been a great consideration since ancient times in iran. the yearly average atmospheric precipitation in iran is around 250 mm considering the total area of the country, it can be estimated that our share of water is 420 x 109 per year. due to evaporation and run off to the sea through rivers and infliction it has been estimated the available water can not be more than 120 ...

This paper deals with control of bulking by chlorination in a laboratory-scale (15l/ d) biological nutrient removal system. Bulking was caused by filamentous organisms characteristic of nutrient removal systems, i.e. Type 0092, Microthrix parvicella and Type 0914. Over a continuous dosing period of 19 d, at 8 mgCl2 /gMLSS.d the diluted sludge volume index (DSVI) decreased from 230 to 48 ml/g. N...

Internal attack of chromium containing alloys in mixed oxygen-chlorine environments occurs by the formation of pores which penetrate down grain boundaries of the alloys. No internal attack was detected in a binary Fe-20 %Cr alloy at 1200 K in environments containing 2500 ppm C12. The rate of internal attack of alloy 800H in such environments was increased by replacing the O2 in the gas by C02 ....

As part of a comprehensive strategy to the welwitindolinone alkaloids possessing a bicyclo[4.3.1]decane core, we report herein concise asymmetric total syntheses of (-)-N-methylwelwitindolinone C isothiocyanate (2a), (-)-N-methylwelwitindolinone C isonitrile (2b), and (-)-3-hydroxy-N-methylwelwitindolinone C isothiocyanate (3a) from a common tetracyclic intermediate. The crucial vinyl chloride ...

The authors conducted a population-based case-control study of 1,068 incident leukemia cases and 5,039 controls aged 20-74 years during 1994-1997 to examine the association between exposure to drinking water chlorination disinfection by-products and adult leukemia risk in Canada. Residence and drinking water source histories and data from municipal water supplies were used to estimate individua...

Many environmental organic chemicals have chloride in their structure. Thus, researching the chlorination mechanism of carbon is of interest. Dioxins are typically concentrated in fly ash collected from the post-combustion zone during the operation of municipal solid waste incinerators. In this study, we report the application of Cl-K near-edge X-ray-absorption fine structure (NEXAFS) in determ...