Multipod gold nanocrystals have been synthesized via a simple solution-phase chemical reduction method at room temperature. Two types of structurally different particles are observed, including the regular tripod, which lies on the substrate with its {111} plane, and the cross-like tetrapod that sits on its {100} plane. Both structures have pods of 10 nm sizes and grow along 110 directions. Var...

We provide a theoretical foundation for the statistical approach for computing the absorption properties of particles in the Rayleigh domain. We present a general method based on the Discrete Dipole Approximation (DDA) to compute the absorption and scattering properties of particles in the Rayleigh domain. The method allows to separate the geometrical aspects of a particle from its material pro...

Nucleation-and-growth processes are used extensively in the synthesis of spherical colloids, and more recently regiospecific nucleation-and-growth processes have been exploited to prepare more complex colloids such as patchy particles. We demonstrate that surface geometry alone can be made to play the dominant role in determining the final particle geometry in such syntheses, meaning that intri...

The novel high-fidelity CFD model for packed bed reactors is validated in terms of Nu regarding particle-to-fluid heat transfer. The model is developed to take into consideration the flow of heat, mass and momentum through and around the particles each shaped without geometrical simplification. In the present approach, cylindrical shaped solid geometries are used to bridge particles in or near ...