A particle in the attractive Coulomb field has an interesting property: its specific heat is constant and negative. We show, both analytically and numerically, that when a classical Hamiltonian system stays in weak contact with one such negative specific heat object, its statistics conforms to a fat-tailed power-law distribution with power index given by C/kB − 1, where kB is the Boltzmann cons...

In this study 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) interaction with carbon nanocone(NC) and nanocone Sheet (NCS) was evaluated by density functional theory. The calculated thermodynamic parameters including Gibbs free energy changes and Enthalpy alterations showed the interaction of TATB with the both nanostructures are exothermic, spontaneous, experimentally possible ...

the kinetics and mechanism of the reaction of 5-nitro-1h-benzo[d] imidazole to produce 6-nitro-1h-benzo[d] imidazole was studied by employing hybrid meta-density functional theory. mpwblk/6-31+g** level calculations were carried out to obtain energies and optimize the geometries of all stationary points along the pes, and determine the harmonic vibrational frequencies. two transition states (ts...

We present a specific heat measurement technique adapted to thin or very thin suspended membranes from low temperature (8 K) to 300 K. The presented device allows the measurement of the heat capacity of a 70 ng silicon nitride membrane (50 or 100 nm thick), corresponding to a heat capacity of 1.4 × 10(-10) J/K at 8 K and 5.1 × 10(-8) J/K at 300 K. Measurements are performed using the 3ω method ...

The thermal properties such as specific heat capacity and heat dissipation of peloids play an important role in therapeutic applications. Therefore, these properties were determined on the peloids samples taken from spas where peloid applications are used in Turkey. In addition, some pure clay minerals were investigated to determine their suitability as possible constituents of therapeutic pelo...

Objective (s): The present study aimed to assess the adsorption of fullerene C24 with Melphalan anticancer agent in a solvent phase (water) at the B3LYP/6-31G (d) theoretical level.Materials and Methods: Initially, the structures of Melphalan and fullerene complexes were optimized in four configurations. Afterwards, IR calculations and molecular orbital analysis were performed. In addition, som...

In this investigation the silicate nano structure of MCM-41 has been used for the production of nanofluid. The particles have negligible heat conductivity and therefore by their dispersion in a base fluid like water, it is possible to study the increase of heat conductivity due to the Brownian motion effects. In this work a suitable apparatus for the measurement of heat conductivity has been bu...

We measured the heat capacity on random alloys of Nd1−xCaxB6 (x < 0.4) in the 0.4 to 300 K temperature range. We calculated the lattice contribution to the specific heat, arising from the Debye-type phonons of the boron framework and Einstein-type oscillators of the cation sublattice. Subtracting lattice and Schottky-type contributions from the measured heat capacity, we find that the electroni...