This work initially focuses on developing a computational fluid dynamics (CFD) model of an industrialscale steam methane reforming reactor (reforming tube) used to produce hydrogen. Subsequently, we design and evaluate three different feedback control schemes to drive the area-weighted average hydrogen mole fraction measured at the reforming tube outlet ( x̄H outlet 2 ) to a desired set-point va...

Transitioning to lower carbon energy and environment sustainability requires a reduction in greenhouse gases such as dioxide (CO2) methane (CH4) that contribute global warming. One of the most actively studied rare earth metal catalysts is cerium oxide (CeO2) which produces remarkable improvements dry reforming methane. This paper reviews management CO2 emissions recent advent trends bimetallic...

Catalytic steam reforming of methane for hydrogen production proceeds even at 473 K over 1 wt% Pd/CeO2 catalyst in an electric field, thanks to the surface protonics. Kinetic analyses demonstrated the synergetic effect between catalytic reaction and electric field, revealing strengthened water pressure dependence of the reaction rate when applying an electric field, with one-third the apparent ...

Dry reforming of methane for the production of hydrogen and syngas has attracted much attention from both industrial and environmental aspects. The major problem encountered in the application of this process is the rapid deactivation of the catalyst, which is mainly due to coke accumulation and sintering of the catalyst. As an alternative to reduce the coke formation, the combination of CO2 re...

Experiments of propane and propene steam reforming have been performed over a Pd–Cu/c-Al2O3 catalyst and over a Ni/NiAl2O4 catalyst. Over the palladium-based catalyst, the steam reforming of propene is faster and more selective than steam reforming of propane. Over the Pd catalyst, the steam reforming of propane is likely inhibited by site poisoning. In contrast, over Ni-based catalyst the refo...

A process scheme based on a series of fixed-bed reactors is presented as a possible alternative for carrying out the chemical looping combustion of methane at high pressure with ilmenite as oxygen carrier. The oxygen carrier is stationary and it is alternately exposed to reducing and oxidizing atmospheres by means of the periodic switching of the gas feeds (i.e., methane and air, respectively)....

This study investigates the feasibility of electricity production in a solid oxide fuel cell using methane recovered from groundwater as fuel. Methane must be removed for drinking water to, amongst others, avoid bacterial regrowth. Instead releasing to atmosphere or converting it carbon dioxide by flaring, can also vacuum stripping and served However, electrical efficiency currently used combus...

A method for the production of clean hydrogen is demonstrated. The process consists of two steps involving the decomposition of methane to CO-free hydrogen and surface carbon in the first step followed by steam gasification of this surface carbon in the second step. This process can be operated in cycles and could be an excellent hydrogen source for fuel cells and other devices or processes req...