Optimization of industrial styrene reactor design for two objectives using the non-dominated sorting genetic algorithm (NSGA) is studied. Both adiabatic and steam-injected reactors are considered. The two objectives are maximization of styrene production and styrene selectivity. The study shows that styrene reactor design can be optimized easily and reliably for two objectives by NSGA. It provi...

In this study, we selected 58 styrene-exposed workers, measured personal styrene exposure, evaluated genotypes relevant drug-metabolizing enzymes (CYP2E1, EPHX1, GSTM1 and GSTT1) which may explain the variability in the urinary metabolite excretion. The results showed that, in different levels of styrene exposure groups, there is a significant association between urinary metabolites and some ge...

In this study, 162 samples were analysed for monomer styrene content with using high performance liquid chromatography (HPLC) method in hot tea, milk, cocoa milk. The monomer styrene content, expressed in microg/l of drink and the level of migration of styrene monomer were varied from 0.61 to 8.15 for hot tea, from 0.65 to 8.30 for hot milk, from 0.71 to 8.65 for hot cocoa milk in GPPS (general...

BACKGROUND Health risks of using styrene to manufacture windblades for the green energy sector are unknown. METHODS Using data collected from 355 (73%) current windblade workers and regression analysis, we investigated associations between health outcomes and styrene exposure estimates derived from urinary styrene metabolites. RESULTS The median current styrene exposure was 53.6 mg/g creati...

In this work, the influence of three types of styrene maleic anhydride (SMA) oligomers on the adhesion of polystyrene wood plastic composites (WPC) was investigated. The composites were processed on a twin-screw co-rotating extruder below 200°C using 20 wt% of wood flour. The styrene maleic anhydride with different content of maleic anhydride groups, 30%, 25% and 20% (w/w) and levels of 1, 2 an...

Environmental chamber experiments and computer model calculations were conducted to assess the impacts of the gas-phase reactions of styrene on the atmospheric formation of ozone and styrene's known oxidation products. The experiments consisted of determining the effects of adding styrene on ozone formation, NO oxidation, integrated OH radical levels, and formation of benzaldehyde, formaldehyde...

Current EPA emission factors (AP42) for styrene emissions from the production of polyester-resin-reinforced plastic products represent a composite of spraying and post-spraying emissions (from curing molds) from shower stall/bathtub manufacturing plants that use compressed-air-powered spray guns to apply catalyzed styrene resins to prepared molds. Because each step of manufacture (gel coating, ...

4-chloromethyl styrene homopolymer and its copolymers with styrene were prepared from their corresponding 4-chloromethyl styrene and styrene monomers at 1:0, 1:1, 1:3 and 1:5 mole ratios. these homo- and copolymerswere synthesized by radical polymerization in presence of aibn as initiator and dry toluene as solvent. then, chloromethyl groups were converted into azidomethyl groups on the homo- a...

Six male subjects were exposed for two hours during light physical exercise to 2.81 mmol/m3 (293 mg/m3) of styrene on one occasion and to a mixture of 2.89 mmol/m3 (301 mg/m3) of styrene and 21.3 mmol/m3 (1240 mg/m3) of acetone on another (combination study). About 68% of the dose (somewhat more than 4 mmol) of styrene was taken up. The arterial blood concentration of styrene reached a relative...