A bacterial strain (strain S5) which grows aerobically with the sulfonated azo compound 4-carboxy-4'-sulfoazobenzene as the sole source of carbon and energy was isolated. This strain was obtained by continuous adaptation of "Hydrogenophaga palleronii" S1, which has the ability to grow aerobically with 4-aminobenzenesulfonate. Strain S5 probably cleaves 4-carboxy-4'-sulfoazobenzene reductively u...

A Fe/Fe3O4/N-carbon composite consisting of a porous carbon matrix containing a highly conductive N-doped graphene-like network and Fe/Fe3O4 nanoparticles was prepared. The porous carbon has a hierarchical structure which is inherited from rice husk and the N-doped graphene-like network formed in situ. When used as an anode material for lithium batteries, the composite delivered a reversible ca...

The use of high surface monolithic carbon as support for catalysts offers important advantage, such as elimination of the ohmic drop originated in the interparticle contact and improved mass transport by ad-hoc pore design. Moreover, the approach discussed here has the advantage that it allows the synthesis of materials having a multimodal porous size distribution, with each pore size contribut...

The activated bamboo char (ABC) was available commercially and carbon nanofibers (CNF) were grown on its surface by a CVD method. The resultant composites were characterized by nitrogen method at 77K and scanning electron microscopy (SEM). The structure of bamboo-based porous carbon might be tunable by adjusting purposively the growth of CNFs. The CNF/ABC composite would combine the properties ...

Nitrogenated porous carbon materials, made by coating the pore surface with nitrogen functional groups from the pyrolysis of hexamine, were characterized and tested for supercapacitor applications. From X-ray photoelectron spectroscopy, the nitrogen content of the nitrogenated carbon sample was found to be 14 wt%. Electrochemical properties from potentiostatic and galvanostatic measurements, an...

Li₄Ti₅O₁₂/activated carbon hybrid supercapacitor can combine the advantages of both lithium-ion battery and supercapacitor, which may meet the requirements for developing high-performance hybrid electric vehicles. Here we proposed a novel "core-shell" porous graphitic carbon (PGC) to replace conventional activated carbon for achieving excellent cell performance. In this PGC structure made from ...

High levels of iron-nitrogen doped porous carbon materials are obtained from MOF-253 using a step-by-step post-synthetic modification strategy. MOF-253 possessing open 2,2'-bipyridine nitrogen sites not only serves as a precursor but also provides chelate bonding sites for Fe2+. Followed by further impregnation of 1,10-phenanthroline, high surface area porous carbon materials are obtained. For ...

Synthesis and characterization of the novel sulfonated BAPPO monomer and its use in the synthesis of a new phosphine oxide-based sulfonated polyimide are described. BTDA, 6FDA, and DDS were used as monomers in the polyimide synthesis. Sulfonated polyimide membranes were obtained by a solution thermal imidization method. The thermal behavior of the polymers was investigated by DSC and TGA. The m...

To explain the fast kinetics of H in porous carbon, we propose that the migration relies on H hopping from a carbon nanotube (CNT) to another. Using density functional theory, we have found that the barrier for H hopping becomes smaller than that for diffusion along a tube for certain CNT separations, decreasing to less than 0.5 eV for separations of 3.1 Å. Such significant reduction occurs irr...