The purpose of this investigation was directed to propose sensitive, accurate and reproducible methods of analysis that can be applied to determine distigmine bromide (DTB), cyclopentolate hydrochloride (CPHC), diaveridine hydrochloride (DVHC) and tetrahydrozoline hydrochloride (THHC) drugs in pure form and pharmaceutical preparations via charge-transfer complex formation with 7,7,8,8-tetracyan...

(C9H7INO • C12H4N4) triclinic PT, a = 7.161(5) A, b = 8.639(5) Ä, c = 17.392(6) A, a 64.96(4)°, ß = 80.64(3)°, y = 76.99(3)°, V = 1075.6 A3, Z = 2, dc = 1.47 Mgm-3. The structure was refined to R — 0.114 for 2022 reflections. It consists of segregated diadic stacks of TCNQ and 4-oxo-iodoquinolinium ions. Interplanar distances in the TCNQ stack are 3.09( 1) A and 3.32(1) A ; 3.37(1) A and 3.55(1...

In this paper, the top-contact (TC) pentacene-based organic thin-film transistor (OTFT) with a tetrafluorotetracyanoquinodimethane (F₄TCNQ)-doped pentacene interlayer between the source/drain electrodes and the pentacene channel layer were fabricated using the co-evaporation method. Compared with a pentacene-based OTFT without an interlayer, OTFTs with an F₄TCNQ:pentacene ratio of 1:1 showed co...

We report the synthesis of small-molecule organic conductor nanowires of TTF-TCNQ by selective inducement in a two-phase method by pi-pi stacking interaction. The morphologies of TTF-TCNQ, from straight nanowires to helical nanowires and to complicated helical dendrite structures, have been controlled by adjusting the experimental conditions. The technique has been applied to the synthesis of A...

The photoelectron spectrum of the 7,7,8,8-tetracyanoquinodimethane (TCNQ) radical anion has been measured at 3.1 eV. Additionally, the ultrafast relaxation dynamics of the first excited state (1(2)B(3u)) of TCNQ(-) have been studied using time-resolved photoelectron spectroscopy, which reveals that it undergoes internal conversion back to the ground state ((2)B(2g)) with an associated lifetime ...

Directional crystallization from the melt has been used as a tool to grow parallel crystalline stripes of p- and n-type molecular semiconductors. To start, phase behavior 2,7-dioctyl[1]benzothieno[3,2-b][1]benzothiophene (C8-BTBT-C8): tetracyanoquinodimethane (TCNQ) blends (molar ratio 20:1 1:1) investigated by variable-temperature X-ray diffraction, differential scanning calorimetry, polarized...

Three systems [Fe(III)(sal2-trien)](TCNQ)n·X (n = 1, 2, X = MeOH, CH3CN, H2O) showing spin-crossover transition, conductivity and ferromagnetic coupling were synthesized and studied by X-ray diffraction, Montgomery method for resistivity, SQUID magnetometry and X-band EPR. Spin-spin interactions between local magnetic moments of Fe(III) ions and electron spins of organic TCNQ network were disco...

The energy-level alignment at interfaces between three electroactive conjugated organic materials and Au was systematically varied by adjusting the precoverage of the metal substrate with the electron acceptor tetrafluoro-tetracyanoquinodimethane (F4-TCNQ). Photoelectron spectroscopy revealed that electron transfer from Au to adsorbed F4-TCNQ was responsible for lowering the hole-injection barr...

Simple, accurate and precise spectrophotometric methods have been developed for the determination of sitagliptin and vildagliptin in bulk and dosage forms. The proposed methods are based on the charge transfer complexes of sitagliptin phosphate and vildagliptin with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ), 7,7,8,8-tetracyanoquinodimethane (TCNQ) and tetrachloro-1,4-benzoquinone (p-chlor...

2014 Electron irradiation of the organic semiconductors of NMePy(TCNQ)2 type produces defects which change their vibrational and electronic spectra. The spectral changes are described and discussed. The electronphonon coupling constant changes are deduced; the defect concentration as well as their volume are calculated from spectral measurements. The role of electron-electron interactions are e...