in this study, we synthesis one-dimensional (1d) manganese(iii) schiff base coordination polymer [mn(brsalophen)(μ1,3-n3)]n by reaction of mncl2·6h2o and tetradentate schiff base ligand brsalophen at the presence of nan3 in methanol and characterized by elemental analyses (chn) and ft-ir spectroscopy. it was used as a new precursor to prepare spinel type manganese oxide nanowires by a facile so...

as a new precursor, [tris(2-hydroxyacetophenato) triaqua(iii)], [y(hap)3(h2o)3]; complex was used in thermal decomposition process for the synthesis of rod-like high-temperature ceramic ybco with length of about 320-350 nm and diameters 60–90 nm. the as-synthesized products were characterized by xrd, ft-ir, tem, sem and edx analyses. the results showed that by using fine raw materials, the calc...

mg(oh)2 nanoparticles were synthesized by a rapid microwave reaction. the effect of sodium dodecyl sulfonate (sds as anionic surfactant) and cetyl tri-methyl ammonium bromide (ctab as cationic surfactant) on the morphology of magnesium hydroxide nanostructures was investigated. multi wall carbon nano tubes was organo-modified for better dispersion in cellulose acetate matrix. the influence of m...

The thermal decomposition of plutonium oxalate to oxide is one the most studied reactions in actinide chemistry but intermediates have been subject debate for decades. Recent experimental data suggest that Pu(IV) air undergoes dehydration first, then reduction Pu(III) oxalate. precise structural modifications take place are unknown as experiments not able fully characterize at microscopic level...

The interaction of reagent grade strontium sulphate and celestine concentrate with aqueous solutions of oxalic acid, sodium oxalate and ammonium oxalate for the production of strontium carbonate were investigated for different oxalate compound:SrSO4 mole ratios and reaction times using x-ray diffraction analysis and dissolution tests. Under the same experimental conditions, it was found that aq...

Simultaneous thermal analysis (STA) method has been applied to study decomposition reactions of AP under a flowing nitrogen atmosphere and static air. Results obtained indicate that a phase transformation occurs prior to the decomposition reaction. Decomposition takes place exothermally in two stages, first stage of decomposition could be suppressed by the controlled heating programme. Addi...

This work investigates the potentialities of thermal analysis (TA) coupled with mass spectrometry (MS) technique by studying decomposition calcium oxalate monohydrate (CaC2O4·H2O). The aim this is twofold: to demonstrate, at first, efficacy coupling gravimetric (TG)-MS experimental approach check presence intermediate reactions beyond conventional three-step decomposition: dehydration, decarbon...