Gels of low molecular weight gelators (LMWGs) are self-assembled, thermoreversible, viscoelastic materials which can also be rendered sensitive to light, pH or chemical substances by simple chemical modifications. In addition, the ability of some of these LMWGs to gelate water (hydrogelators) makes these gels interesting, new materials for drug delivery applications. In this paper, for the firs...

We experimentally and theoretically investigate the size effect of gelation using Resorcinol-Formaldehyde aerogels. We find a clear dependence of gelation time on the sample size under mild shear conditions. We developed a theoretical model based on Smoluchowski’s aggregation model adding, however, a growth term which accounts for the continuous growth of the colloidal particles while clusterin...

Gels of low molecular weight gelators (LMWGs) are self-assembled, thermoreversible, viscoelastic materials which can also be rendered sensitive to light, pH or chemical substances by simple chemical modifications. In addition, the ability of some of these LMWGs to gelate water (hydrogelators) makes these gels interesting, new materials for drug delivery applications. In this paper, for the firs...

Amylomaltases are 4-alpha-glucanotransferases (EC 2.4.1.25) of glycoside hydrolase family 77 that transfer alpha-1,4-linked glucans to another acceptor, which can be the 4-OH group of an alpha-1,4-linked glucan or glucose. The amylomaltase-encoding gene (PAE1209) from the hyperthermophilic archaeon Pyrobaculum aerophilum IM2 was cloned and expressed in Escherichia coli, and the gene product (Py...

Titanium dioxide nano-particles were synthesized via the sol-gel method using titanium butoxide as the precursor. Acid catalyzed and aged gels were dried under air to produce xerogels and under supercritical conditions to produce aerogels. Porous particles obtained were characterized using X-ray diffraction, SEM and BET analysis. Aerogel powder was found to have more favorable properties compar...

BACKGROUND AND OBJECTIVES Rheological evaluation of thermoreversible mucoadhesive nasal gel of zolmitriptan is done to determine the steady shear behaviour and gelation temperature. The thermoreversible mucoadhesive polymers are sucessesfully used to increase the contact time of the therapeutic compound in the nasal cavity as well as they cause enhancement in permeation of drug through the nasa...

INTRODUCTION:  Novel semisolids are non greasy since they are made up of water washable bases. Hence they cause less irritation to skin and are superior to conventional semisolid dosage form.  Novel creams now a days are provided with nanoparticles and microspheres, which has an excellent emollient effect, with better spreadability, and less staining than oleaginous ointments. However both me...

Three new bicomponent hydrogels of riboflavin (R) with salicylic acid (S), dihydroxybenzoic acid (B) and acetoguanamine (D) in 1:1 molar ratio have been reported. FTIR and UV-vis spectra suggest formation of H-bonded complexes in 1:1 molar ratio of the components. The network consists of tape, bar and helical tubes for RB11, RS11 and RD11 systems, respectively. Reversible first order phase tran...

2014 In order to explain the temperature dependence of elasticity of thermo-reversible gels, a simple model is proposed It assumes that the gel consists of Langevin chains whose both ends are loosely fixed in crystalline junction regions in such a way that the segments near each end are bound densely in one of the junction region. The segments are assumed to be released from the junction with i...