Half sandwich complexes of titanium bearing eta1 or eta2 bound nitroxide ligands are highly active catalysts for the polymerisation of propylene to high molecular weight atactic poly(propylene).

A series of new titanium half sandwich complexes, containing a 2-aminopyrrolinato ligand {N(Xyl)N}(-) as the ancillary ligand, have been prepared and are shown to be pre-catalysts for the hydroamination of alkynes. The coordination of {N(Xyl)N}(-) to titanium was achieved by reaction of [Cp*TiMe(3)] with the protioligand N(Xyl)NH giving [Cp*Ti(N(Xyl)N)(Me)(2)] (). Upon reaction of complex with ...

Novel Mg (0.58, 0.97, 1.98 and 2.5) vol. % TiN nanocomposites containing titanium nitride (TiN) nanoparticulates of ~20 nm size are successfully synthesized by a disintegrated melt deposition technique followed by hot extrusion. Microstructural characterization of Mg-TiN nanocomposites indicate significant grain refinement with Mg 2.5 vol. % TiN exhibiting a minimum grain size of ~11 μm. X-ray ...

Next generation cathode catalysts for direct methanol fuel cells (DMFCs) must have high catalytic activity for the oxygen reduction reaction (ORR), a lower cost than benchmark Pt catalysts, and high stability and high tolerance to permeated methanol. In this study, palladium catalysts supported on titanium suboxides (Pd/TinO2n-1) were prepared by the sulphite complex route. The aim was to impro...

Titanium and its alloys are widely used in modern supersonic aircraft rockets, submarines ships, the chemical food industries, as well other areas of technology. In process obtaining titanium from ore, workers may be exposed to metal dust (Ti) dioxide (TiO2), highly toxic compounds – gaseous tetrachloride (TiC14), hydrolysis products, chlorine phosgene vapors. The study influence produc-tion co...

A characterization of Ti-Beta zeolites synthesized under various conditions as well as an investigation of their photocatalytic properties for the reduction of CO2 with H2O at 323 K to produce CH4 and CH3OH were carried out. In situ XAFS spectra measurements indicated that a highly dispersed tetrahedral titanium oxide species was present in the zeolite framework and an increase in the coordinat...

A synthetic route to magnesium guanidinate compounds that avoids ligand redistribution is reported; selected derivatives are active pre-catalysts in the dimerization of aldehydes.

INTRODUCTION Jaundice is a disease named for the yellow color of the skin. This color is the result of elevated levels of bilirubin in the blood serum. In Roma from Krusevac region in the last few years have seen the emergence of jaundice. MATERIAL AND METHODS In 80 of them (40 suffering and 40 from control group) were performed tests of numerous parameters in the laboratories of the Health C...

Magnesium alloys are candidates for resorbable material in bone fixation. However, the degradation and performance of osteosynthesis plate/screw systems in vivo, under cyclic deformation, is unknown. We evaluated the outcomes of human standard-sized magnesium plate/screw systems with or without plasma-electrolytic surface modifications in a miniature pig rib model. Of a total of 14 minipigs, si...