Complexation reactions of titanium tetraethoxide [Ti(OEt)4] and titanium tetra-n-butoxide [Ti(OBu )4] with 3-pentenoic acid (PA) and allylacetoacetate (AAA), in a 1 : 1M ratio, were studied in ethanol solution at room temperature. C-NMR and FTIR spectra showed that all PA and AAA completely reacted with both titanium alkoxides. Hydridosilane compounds such as triethoxysilane and triethylsilane ...

INFLUENCE OF FLUORIDE AND STRESS ON THE ELECTROCHEMICAL PROPERTIES OF NICKEL-TITANIUM COILS Ashley Barnes Marquette University, 2015 The aim of this study was to examine the effects of fluoride and stress on the electrochemical properties of nickel-titanium coils. Forty Dentsply GAC NiTi coils were divided into four groups of ten and individually tested. Twenty coils were placed in a solution o...

A highly efficient tetra-(n-butyl)ammonium fluoride (TBAF)-promoted intramolecular cyclization of gem-dibromoolefins has been developed for the synthesis of 2-bromobenzofused heterocycles. The reaction provides a convenient approach to 2-bromobenzofurans(thiophenes) from the corresponding readily available gem-dibromovinyl substrates without a metal.

Resin-supported [18F]fluoride ion has been prepared and applied to a rapid, convenient synthesis of [18F]FDG. "No-carrier-added" [18F]fluoride ion is collected on a quaternary 4-(N,N-dialkylamino)-pyridinium functionalized polystyrene anion exchange resin directly from a [18O]water target, dried by rinsing with acetonitrile, and then reacted with 1,3,4,6-tetra-O-acetyl-2-O-trifluoromethanesulfo...

Titanium plates treated in vitro with a mouthwash containing amine fluoride (100 ppm F-) and another containing zinc-substituted carbonate-hydroxyapatite have been analyzed by scanning electron microscopy and atomic force microscopy to evaluate the modification of the surface roughness induced by treatment with these two different mouthwashes. The treatment with F--based mouthwash produces a ro...

This paper presents titanium dioxide nanostructured surfaces prepared in organic electrolytes containing ammonium fluoride by anodic oxidation method. Two approaches were used for fabrication, one-step and two-step anodization. The obtained TiO2 surfaces have nanoporous structure. The morphology of anodized TiO2 nanostructures was characterized by scanning electron microscopy (SEM).

Nanofibers, produced by electrospinning a solution containing titanium tetra(IV) isopropoxide, polyvinyl acetate and acetic acid in N,N-dimethyl acetamide, upon sintering at 500 °C produce rice grain-shaped TiO(2) mesostructures. Each rice grain-shaped TiO(2) has a mixed crystal structure and high porosity and the mesostructures are found to have applications in dye-sensitized solar cells.

In article 2100068, S. T. Britt and P. C. Pistorius study liquid titanium-bearing iron (saturated with carbon) wets alumina crucibles. Wetting is caused by reaction between dissolved titanium alumina; it can be prevented pre-treating the crucible a flux containing calcium fluoride. By avoiding wetting, clear images of carbide formation on droplet obtained, during confocal scanning laser microsc...