The structure of the title compound, [Ni(C(15)H(14)N(3)S(2))(2)]·H(2)O, has one mol-ecule in the asymmetric unit, along with a solvent water mol-ecule. The two different Schiff base moieties coordinate to the central Ni(II) ion as tridentate N,N',S-chelating ligands, creating a six-coordinate distorted octa-hedral environment [the smallest angle being 77.43 (7)° and the widest angle being 169.9...

The chemistry of the iron complexes of two Schiff-base ligands namely, N-2-mercaptophenyl-20-pyridylmethylenimine (PyASH, 1) and N-2-mercapto-2-methylpropyl-20-pyridylmethylenimine (PyMSH, 2) has been explored in a systematic manner. Use of DMF as solvent allows one to isolate the Fe(II) complexes in pure forms. The Fe(III) complexes [Fe(PyAS)2]X (X ˆ BF4, BPh4 (3)) and [Fe(PyMS)2]BPh4 (4) have...

Two Schiff base ligands L1and L2 were obtained by the condensation of glycylglycine respectively with imidazole-2-carboxaldehyde and indole-3-carboxaldehyde and their complexes with Zn(II) were prepared and characterized by microanalytical, conductivity measurement, IR, UV-Vis., XRD and SEM. The molar conductance measurement indicates that the Zn(II) complexes are 1: 1electrolytes. The IR data ...

The current work reports the synthesis, spectroscopic studies, antiradical and antiproliferative properties of four ruthenium(III) complexes of heterocyclic tridentate Schiff base bearing a simple 2',4'-dihydroxyacetophenone functionality and ethylenediamine as the bridging ligand with RCHO moiety. The reaction of the tridentate ligands with RuCl₃·3H₂O lead to the formation of neutral complexes...

New coordination complexes of Co, Ni and Zn with Schiff base N’-((2-thioxo-1,2-dihydroquinoline-3yl)methylene) pyridine-4-carbohydrazide have been synthesized and characterized by several techniques using elemental analysis (C, H, N), IR spectra and 1HNMR spectra. The new Schiff base has been synthesized by the reaction of pyridine-4-carbohydrazide and 2-thioxo-1,2dihydroquinoline-3-carbaldehyd...

Two new azide bound cobalt(III) complexes, [Co(L(1))(N3)3] (fac-1) and [Co(L(2))(N3)3] (mer-2), where L(1) is bis(2-pyridylmethyl)amine and L(2) is (2-pyridylmethyl)(2-pyridylethyl)amine, derived from tridentate reduced Schiff-base ligands have been reported. Interestingly, a methylene bridge regulated preferential coordination mode of ligands is noticed in their crystal structures: it is found...

The synthesis, structure and photophysical properties of two polynuclear zinc complexes, namely [Zn6L2(µ3-OH)2(OAc)8] (1) [Zn4L4(µ2-OH)2](ClO4)2 (2), supported by tridentate Schiff base ligand 2,6-bis((N-benzyl)iminomethyl)-4-tert-butylphenol (HL) are presented. synthesized compounds were investigated using ESI-MS, IR, NMR, UV-vis absorption spectroscopy, photoluminescence spectroscopy single-c...