This article describes one-pot synthesis of new fluorinated hexahydroquinoline derivatives via unsymmetric Hantzsch reaction involving 5-trifluoromethyl-1,3cyclohexanedione, aldehydes, acetoacetate ester, and ammonium acetate in trifluoroethanol (TFE). The reaction is simple and rapid with high yield.

Unsymmetric and symmetric diaryliodonium triflates are synthesized from both electron-deficient and electron-rich substrates in a fast, high yielding, and operationally simple protocol employing arenes and aryl iodides or iodine.

Multifrontal is an efficient direct method for solving large-scale sparse and unsymmetric linear systems. The method transforms a large sparse matrix factorization process into a sequence of factorizations involving smaller dense frontal matrices. Some of these dense operations can be accelerated by using a graphic processing unit (GPU). We analyze the unsymmetricmultifrontalmethod fromboth an ...

Density functional theory, Complete Active Space Self-Consistent Field (CASSCF) and perturbation theory (CASPT2) methodologies have been used to explore the electronic structure of a series of trichromium Extended Metal Atom Chains (EMACS) with different capping ligands. The study is motivated by the very different structural properties of these systems observed in X-ray experiments: the CN--ca...

| We mainly examine the application of the improved version of the quasi-minimal residual (IQMR) method 20], 21] for the solutions of linear systems of equations with unsymmetric coeecient matrices arising from the discretization of uid dynamic problems on massively parallel distributed memory computers. We will deal with implicit nite diierence schemes for solving the Euler equations. These sc...

A Krylov subspace projection method which provides simultaneous solutions of the Helmholtz equation at multiple frequencies in one solution step is presented. The projector is obtained with an unsymmetric block Lanczos algorithm applied to a transfer function derived from a finite element discretization. This approach is equivalent to a matrixvalued Pad e approximation of the transfer function....