The Antoine equation is a semi-empirical equation which expresses vapour pressure as a function of temperature. A new, rapid and highly accurate method for obtaining its three constants from experimental data is presented and applied to ethanol, water and 14 anaesthetic substances. Alternative vapour pressure equations are discussed and references for original temperature--vapour pressure data ...

The isotope composition of water vapour: A powerful tool to study transport and chemistry of middle atmospheric water vapour Ch. Bechtel and A. Zahn Institut für Umweltphysik, University of Heidelberg, Heidelberg, Germany Institute of Meteorology and Climate Research, Forschungszentrum Karlsruhe, Germany Received: 11 June 2003 – Accepted: 16 July 2003 – Published: 28 July 2003 Correspondence to...

The terrestrial embryos of many amphibians obtain water in two ways; in a liquid phase from the substrate on which eggs are deposited, and in a vapour phase from the surrounding atmosphere. We tested whether the mode of water flux (liquid or vapour) affected the morphology and metabolic traits of the terrestrial Victorian smooth froglet (Geocrinia victoriana) embryos by incubating eggs both wit...

We present observations of the 313 →220 line of p-H2O at 183 GHz in the direction of the circumstellar envelopes of 23 O–rich evolved stars. The 183 GHz data are complemented with observations of CO J=2 →1, p-H2O 515 →422 at 325 GHz, o-H2O 616 →523 at 22 GHz and SiO v=1 J=2 →1. The line profiles of these transitions are compared and discussed in terms of the regions where they are formed. We ha...

The isotopic compositions of water vapour and its condensates have long been used as tracers of the global hydrological cycle, but may also be useful for understanding processes within individual convective clouds. We review here the representation of processes that alter water isotopic compositions during processing of air in convective updrafts and present a unified model for water vapour iso...

To estimate integrated precipitable water vapour along with liquid water path and water vapour effective profile (i.e. standard atmospheric profile approximation), utilising the SSM/I and TMI radiometers, an operative procedure was developed and assessed. This procedure is based on a fast nonlinear physical inversion algorithm (PIn) developed by the authors. A large data-set of near-coincident ...

An accurate characterization of the vertical structure of the Arctic atmosphere is useful in climate change and attribution studies as well as for the climate modelling community to improve projections of future climate over this highly sensitive region. Here, we investigate one of the dominant features of the vertical structure of the Arctic atmosphere, i.e. water-vapour inversions, using eigh...

Econometrics has a long history as the technique of choice for testing the merits of alternative hypotheses across most of the social sciences as well as many of the natural and materials sciences, not to mention pharmaceutical science, where it is widely used to evaluate the efficacy of alternative medications, including the use of placebos as counterfactuals. However its greatest value is in ...

Liquid/vapour interfaces govern the behaviour of a wide range of systems but remain poorly understood, leaving ample margin for the exploitation of intriguing functionalities for applications. Here, we systematically investigate the role of liquid/vapour interfaces in the transport of water across apposing liquid menisci in osmosis membranes comprising short hydrophobic nanopores that separate ...

The STARTWAVE (STudies in Atmospheric Radiative Transfer and Water Vapour Effects) project aims to investigate the role which water vapour plays in the climate system, and in particular its interaction with radiation. Within this framework, an ongoing water vapour database project was set up which comprises integrated water vapour (IWV) measurements made over the last ten years by ground-based ...