The morphology and electrical properties of orthorhombic β-WO3 nanoflakes with thickness of ~7 to 9 nm were investigated at the nanoscale with a combination of scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), current sensing force spectroscopy atomic force microscopy (CSFS-AFM, or PeakForce TUNA™), Fourier transform infra-red absorption spectroscopy (FTIR), linear...

We report a novel type of WO3 nanostructure, i.e. nanorolls obtained as a self-assembled thin film on a transparent conductive substrate. The mild conditions of preparation, avoiding the use of HCl, result in an eco-friendly hydrothermal method with reduced crystallization time. FESEM and HR-TEM show that WO3 nanocrystals are made of rolled nanoflakes with a telescope-like appearance at their t...

We present an organic light emitting diode with a perforated WO3 hole injection layer to improve the light extraction efficiency. The two-dimensionally perforated WO3 layer was fabricated by use of colloidal lithography. The light extraction efficiency was improved due to Bragg scattering of waveguide modes and surface plasmon polaritons, and the operating voltage was also decreased. As a resul...

A series of supported WO3 catalysts were synthesized by incipient wetness impregnation of ammonium metatungstate aqueous solutions onto Al2O3, TiO2, Nb2O5, and ZrO2 supports as a function of tungsten oxide loading. The resulting solid acid catalysts were physically characterized with in situ Raman and UV–vis spectroscopy and chemically probed by methanol dehydration to dimethyl ether (CH3OH-TPS...

WO3 films were obtained via evaporation-induced self-assembly (EISA) using ionic surfactants such as long-chain ionic liquids 1-hexadecyl-3-methyl imidazolium chloride and bromide (C16mimCl and C16mimBr, respectively) and cetyltrimethylammonium chloride and bromide (CTAC and CTAB, respectively) as additives. Owing to the presence of the ionic surfactants, WO3 films crystallize in a preferred or...

One of the technological challenges for hydrogen sensors is long-term stability and reliability. In this article, the UV-light irradiation was introduced into the hydrogen sensing process based on water photolysis effect of Pt/WO3. Ascribing to that, fiber optic hydrogen sensor with Pt/WO3 nanosheets as the sensing element was demonstrated with significantly improved performance of stability. U...

Microsupercapacitors (MSCs) are promising energy storage devices to power miniaturized portable electronics and microelectromechanical systems. With the increasing attention on all-solid-state flexible supercapacitors, new strategies for high-performance flexible MSCs are highly desired. Here, we demonstrate all-solid-state, flexible micropseudocapacitors via direct laser patterning on crack-fr...

High-quality one-dimensional WO3/CdS core/shell nanowire arrays used as photoanodes in photoelectrochemical (PEC) cells were for the first time prepared via a rational, two-step chemical vapor deposition process. The narrow band-gap CdS shell was homogeneously coated on the entire surface of as-grown WO3 core nanowire arrays, forming coaxial heterostructures. The one-dimensional core/shell hete...

The goal of this study is to characterize the Raman spectra of tungsten trioxide (WO3) at increasing temperatures in the range 30.6–170 ̊C in order to understand the behavior and characteristics of WO3 after adsorption of toxic gases (e.g. NO and SO2) and to provide a database of Raman spectral features for future use in providing an optical complement to semi-conducting metal oxide gas sensor t...

A series of model-supported WO3 catalysts were synthesized on preformed Al2O3, Nb2O5, TiO2, and ZrO2 supports by impregnation of aqueous ammonium metatungstate, (NH4)10W12O41·5H2O. The molecular and electronic structures of the supported tungsten oxide phases were determined with in situ Raman and UV–vis spectroscopy, respectively. The supported tungsten oxide structures are the same on all oxi...