Iron incorporated zeolites were prepared from Na-A type zeolite synthesized from melting slag and FeCl3 solution and applied as adsorbents for NH3 and H2S gases. Iron incorporated zeolite was pelletized, calcined and used for gas adsorption experiment. XRD analyses of the zeolite revealed that Fe3þ concentration of solution more than 90mM could destruct the zeolite network structure. It was obs...

Preparative high pressure liquid chromatography on US-Y zeolite shape-selective molecular sieve was studied for carbon isotopic fractionation e€ects. We tested a standard mixture [17b, 21b(H)-hopane, 5a-cholestane] and complex natural hydrocarbon mixtures dominated by tetraand pentacyclic triterpenoids extracted from Oxford Clay shales. We con®rmed that steroids and hopanoids were separated on ...

Measurement by impedance spectroscopy of the changes in intrazeolitic cation motion of pressed pellets of zeolite particles upon adsorption of dimethylmethylphosphonate (DMMP) provides a strategy for sensing DMMP, a commonly used simulant for highly toxic organophosphate nerve agents. In this work, two strategies for improving the impedance spectroscopy based sensing of DMMP on zeolites were in...

The nitric oxide (NO) removal capacity of ion-exchanged zeolite Y obtained from coal combustion fly ash was evaluated in this work. Zeolite Y was exchanged either with Cu or Fe to obtain two different catalysts for the selective catalytic reduction of NOx from flue gas. The selective catalytic reduction experiments were carried out at temperatures ranging from 50°C to 350°C, water content 0% an...

Dye-exchanged Y zeolite is shown to be an effective medium to control the stereoselectivity in the photooxygenation of chiral oxazolidinone-functionalized Z/E-1 enecarbamates. An enantioselectivity (ee) as high as 80% was observed in the methyldesoxybenzoin (MDB) product, obtained in the methylene-blue-exchanged NaY zeolite at room temperature. The efficacy of the asymmetric induction in the MD...

Fast (>I2 kHz) magic-angle-spinning NMR with IH' 7AI cross-polarization quantitatively monitors several aluminous species in dealuminated zeolite Y; the non-framework matter contains 4-, 5-and 6-coordinated A1 and the *7AI signal at 30 ppm is an independent resonance probably due to 5-coordinated non-framework Al and not part of a second-order quadrupole lineshape as previously reported. Since ...

MnTiO3-Zeolite-Y nanocomposites were synthesized with 5-10-20% (w/w) of MnTiO3 by stearic acid gel method. Then, the gels were calcined at 900 °C for 4 hours and the resulted spectra were investigated at 20% (w/w) concentration. Also, the presence of rhombohedral phase of MnTiO3 in Zeolite-Y matrix was confirmed by XRD, SEM, EDX and BET. The VSM results showed t...

In addition to their well-known uses as catalysts, zeolites are utilized to adsorb and remove various cations from aqueous system. The adsorption of the cations is ascribed to the negative charge of zeolites derived from isomorphous substitution of Si by Al. The amount of Na+ adsorption on 4A, X, Y, Na-P1 and mordenite type zeolites were determined in aqueous media, in a two-cation (Na+ and H+)...

a type of zeolite from the analcime family was prepared by using triethanolamine, silica gel and sodium aluminate. the average particle size was around 24 µm. ftir, xrd and sem results approved the type of zeolite which was formed

Mesoporous aggregates of nanocrystalline zeolites with MFI and BEA frameworks have been synthesized using a one-pot and single structure directing agent. The effect of different reaction conditions, such as temperature, time, pH and water content, on the particle size, surface area and mesopore volume has been studied. Nanocrystalline and mesoporous ZSM-5, β and Y zeolites were modified with di...