An overview on the developments of zirconium phosphate (ZrP) and its organic derivatives in heterogeneous catalysis in recent years is reported in the present review. Two basic aspects have been emphasized: first, the catalytic properties of zirconium phosphates were discussed, with particular attention to the effect of surface acidity and hydrophobic/hydrophilic character, textural properties,...

We report results of simulations on the formation of simple zirconium iodide molecules. Previous work by Wimmer et al. [1] explored the relationship between iodine and a zirconium surface. We investigate the reaction schemes through atomistic simulations to better understand the nature of Zr-I interactions through isolated molecules. The computed energy values of varying Zr-I systems suggests a...

AIMS To report the appearances of zirconium dioxide and barium sulphate in interface membranes, synovium, and other tissues around joint prostheses. METHODS Histological sections from 23 specimens were reviewed by light microscopy and polarisation. Scanning electron microscopy and x ray microanalysis were performed on routinely processed paraffin wax sections. RESULTS Polyethylene, metals, ...

The mechanical properties and good biocompatibility of zirconium and some of its alloys make these materials good candidates for biomedical applications. The attractive in vivo performance of zirconium is mainly due to the presence of a protective oxide layer. In this preliminary study, the surface of pure zirconium modified by anodisation in acidic media at low potentials to enhance its barrie...

A 51 yr old, nonsmoking female suffered from relapsing progressive pneumonia for several years. The patient had worked for 16 yrs in the nuclear industry and was exposed to grinding particles and welding fumes working with zirkaloy, an alloy containing tin, iron, chromium and zirconium. During an exacerbation of the pneumonia radiography of the lung showed interstitial infiltrations of both low...

Modification of different zirconium propoxide precursors with H(2)dea was investigated by characterization of the isolated modified species. Upon modification of zirconium n-propoxide and [Zr(O(n)Pr)(O(i)Pr)(3)((i)PrOH)](2) with (1/2) a mol equivalent of H(2)dea the complexes [Zr(2)(O(n)Pr)(6)(OCH(2)CH(2))(2)NH](2) (1) and [Zr(2)(O(n)Pr)(2)(O(i)Pr)(4)(OCH(2)CH(2))(2)NH](2) (2) were obtained. Ho...

Films of highly oriented alpha-zirconium phosphate and polyaniline-intercalated zirconium phosphate with controllable thickness in the micrometer range were grown anodically on Pt electrodes. To optimize the electrodeposition conditions, the exfoliation of alpha-zirconium phosphate by tetrabutylammonium (TBA) salts was investigated in several nonaqueous solvents. Acetonitrile was found to be th...

Two new intercalates of tris[4-(pyridin-4-yl)phenyl]amine (TPPA) with zirconium hydrogen phosphate and zirconium 4-sulfophenylphosphonate having formulae Zr(HPO4)2·0.21(C33H24N4)·2.5H2O and Zr(HO3SC6H4PO3)(1.3)(C6H5PO3)(0.7)·0.35(C33H24N4)·2.5H2O were prepared and characterized by thermogravimetry, IR spectroscopy, and powder X-ray diffraction. The TPPA molecule has been selected as a model tri...

Ternary hybrid film composed of -zirconium phosphate nanosheet, 1,2-bis(dimethylchlorosilyl)ethane and polypyrrole was prepared by anodic electrodeposition. In the hybrid film, ordered -zirconium nanosheets with grafts by silylation lay down parallel to the substrate and the polypyrrole molecules were intercalated between the nanosheets. The electrochemical measurements confirmed that the hyb...

Investigations of voltammetry zirconium deposition from DMSO solution on different substrates were taken. It was found that this is multi-electron process proceeding in a few stages. Moreover, zirconium layers were obtained on titanium, copper stainless steel and nickel. Obtained deposit was in form of white powder, which immediately was oxidized to ZrO2 in the presence of air.